2-(Bis-chloracetaminomethyl)-thiophen | 90347-16-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 2-(Bis-chloracetaminomethyl)-thiophen
• 英文别名: Thiophenyl-methyliden-(2)-bis-chlor-acetamid；2,2'-dichloro-N,N'-(thiophen-2-yl-methanediyl)-bis-acetamide
• CAS: 90347-16-3
• 化学式: C₉H₁₀Cl₂N₂O₂S
• 分子量: 281.163
• InChiKey: JPNUNDFKBGEXPA-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  2-(Bis-chloracetaminomethyl)-thiophen 、 亚磷酸三乙酯 反应 3.0h， 生成 [({[2-(Diethoxy-phosphoryl)-acetylamino]-thiophen-2-yl-methyl}-carbamoyl)-methyl]-phosphonic acid diethyl ester
  参考文献：
  名称：

  ARYLIDENE BIS-(N-DIETHYL PHOSPHONOACETAMIDES). SYNTHESIS AND NMR CHARACTERIZATION

  摘要：

  Arylidene bis-(N-diethylphosphonoacetamides) have been prepered in good yield. All compounds are white crystalline powders soluble in low boiling point organic solvents. Characterization by H-1-NMR technique indicates that the methyne proton appears in the aromatic region of the spectrum and the two methylene diastereotopic protons (CH2P) give rise to a complex ABX system due to the coupling with the phosphorus atom, thus this pattern is very diagnostic for this tipe of compounds. The heteronuclear coupling was also investigated by H-1{P-31}-NMR spectroscopy.

  DOI：

  10.1080/10426500008046616