(3,5-dimethylpyridine-N)(N-salicylideneglycinato-O,N,O':O'')copper(II) | 193759-26-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (3,5-dimethylpyridine-N)(N-salicylideneglycinato-O,N,O':O'')copper(II)
• 英文别名: Cu(N-salicylideneglycinate)(3,5-dimethylpyridine)
• CAS: 193759-26-1
• 化学式: C₁₆H₁₆CuN₂O₃
• 分子量: 347.861
• InChiKey: MIBLVAVHKZMHOB-XKYXOGKGSA-L

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡啶 、 aqua(N-salicylidene-glycinato-O,N,O')copper(II) hemihydrate 以 乙醇 为溶剂， 生成 (3,5-dimethylpyridine-N)(N-salicylideneglycinato-O,N,O':O'')copper(II)
  参考文献：
  名称：

  Copper(II) salicylideneglycinate complexes as potential antimicrobial agents

  摘要：

  The reaction of an ethanolic solutions of N-salicylideneglycinatoaquacopper(II) hemihydrate with urea, pyridine, 2,4-dimethylpyridine, 3,5-dimethylpyridine, quinoline, 4-methylquinoline, isoquinoline, or 3-methylisoquinoline in an equimolar ratio resulted in solid products containing complexes of the type Cu(salgly)L with distorted square pyramidal coordination polyhedra. The products were characterized by elemental analysis, electronic and EPR spectra, and magnetic susceptibility measurements. Moreover, the crystal and molecular structure of N-salicylideneglycinatoureacopper(II) dimer was determined by single crystal Xray diffraction methods. The copper(H) atoms are bridged by two phenolic oxygen atoms with a Cu-Cu distance of 3.1093(11) Angstrom and Cu-O-Cu angle of 94.47(12)degrees. The antimicrobial effects have been tested on various strains of bacteria, yeasts and filamentous fungi. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01062-9