Mn(phthalocyanine)(2-amino-3-picoline)*(2-amino-3-picoline) | 1200310-57-1

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: Mn(phthalocyanine)(2-amino-3-picoline)*(2-amino-3-picoline)
• CAS: 1200310-57-1
• 化学式: C₆H₈N₂*C₃₈H₂₄MnN₁₀
• 分子量: 783.756
• InChiKey: UFDULCRBSIAAQX-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Mn(phthalocyanine)(2-amino-3-picoline)*(2-amino-3-picoline) 在 air 作用下， 以 吡啶 为溶剂， 生成 μ-oxo-bis[phthalocyaninato(2-)]manganese(III)
  参考文献：
  名称：

  Isomorphic complexes formed by recrystallisation of M(II)Pc (M(II)=Mg, Mn and Zn) in liquid 2-amino-3-picoline

  摘要：

  Three isomorphic, Mg, Mn and Zn phthalocyaninato complexes monoaxially ligated by 2-amino-3-picoline (2A3P) are obtained. They crystallise with 2A3P molecule as solvent molecule in the centrosymmetric space group P2(1)/c of monoclinic system. The central M(II) atom in these complexes, M(II)Pc(2A3P), is coordinated by four isoindole N atoms of Pc macrocycle in equatorial position, and by ring N atom of 2A3P molecule in an axial position. The M(II) due to the interaction with an axial 2A3P molecule is significantly displaced from the plane defined by four isoindole N atoms of Pc macrocycle toward the ring N atom of 2A3P molecule. The stability of these complexes in solid was analysed by thermogravimetric measurements. The Mg and Zn complexes in solution are stable under air condition, while the Mn complex is moderately stable ill Solution and after several days transforms into mu-oxo manganese(III) phthalocyanine complex. The magnetic susceptibility of the MnPc(2A3P) x 2A3P complex shows the Curie-Weiss behaviour in the temperature range of 300-75 K. The calculated mu(eff) indicates on high-spin complex. Below 75 K, the mu(eff) drastically lowered to the value of similar to 3.62 mu(B) indicating the intermediate-spin complex. In addition, the co-crystals of 2:1 composition of 2A3P:1,2-dicyanobenzene were isolated during the preparation of the MgPc(2A3P) x 2A3P. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.08.007
• 作为产物：
  描述：

  2-氨基-3-甲基吡啶 、 酞氰镁 以 neat (no solvent) 为溶剂， 生成 Mn(phthalocyanine)(2-amino-3-picoline)*(2-amino-3-picoline)
  参考文献：
  名称：

  Isomorphic complexes formed by recrystallisation of M(II)Pc (M(II)=Mg, Mn and Zn) in liquid 2-amino-3-picoline

  摘要：

  Three isomorphic, Mg, Mn and Zn phthalocyaninato complexes monoaxially ligated by 2-amino-3-picoline (2A3P) are obtained. They crystallise with 2A3P molecule as solvent molecule in the centrosymmetric space group P2(1)/c of monoclinic system. The central M(II) atom in these complexes, M(II)Pc(2A3P), is coordinated by four isoindole N atoms of Pc macrocycle in equatorial position, and by ring N atom of 2A3P molecule in an axial position. The M(II) due to the interaction with an axial 2A3P molecule is significantly displaced from the plane defined by four isoindole N atoms of Pc macrocycle toward the ring N atom of 2A3P molecule. The stability of these complexes in solid was analysed by thermogravimetric measurements. The Mg and Zn complexes in solution are stable under air condition, while the Mn complex is moderately stable ill Solution and after several days transforms into mu-oxo manganese(III) phthalocyanine complex. The magnetic susceptibility of the MnPc(2A3P) x 2A3P complex shows the Curie-Weiss behaviour in the temperature range of 300-75 K. The calculated mu(eff) indicates on high-spin complex. Below 75 K, the mu(eff) drastically lowered to the value of similar to 3.62 mu(B) indicating the intermediate-spin complex. In addition, the co-crystals of 2:1 composition of 2A3P:1,2-dicyanobenzene were isolated during the preparation of the MgPc(2A3P) x 2A3P. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.08.007