| 1117878-04-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• CAS: 1117878-04-2
• 化学式: C₁₁H₂₁NO₂S
• 分子量: 231.359
• InChiKey: IRJCNCNQOAYYLE-HBNTYKKESA-N

反应信息

• 作为产物：
  描述：

  (2R)-2-[(1S)-1-methyl-5-methyl-5-[(trimethylsilyl)methyl]-4-pentenyl]-N-[methylsulfonyl]aziridine 在 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 生成 、 、
  参考文献：
  名称：

  Substitution effects in intramolecular aziridine–allylsilane cyclizations

  摘要：

  We report here the synthesis of an aziridine tethered to a substituted allylsilane via a substituted tether. These tether-substituted aziridine-allylsilanes cyclize differently upon treatment with BF3.OEt2 than tether-unsubstituted aziridine-allylsilanes and provide a 6-endo-type product. We show that steric interactions between the N-substituent of the aziridine and substitution on the tether can control the product distribution. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2008.11.043