([2,6-bis(dimethylamino)methyl]phenyl)Sn(Ph)[(OBPh)₂O] | 1420352-52-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: ([2,6-bis(dimethylamino)methyl]phenyl)Sn(Ph)[(OBPh)₂O]
• CAS: 1420352-52-8
• 化学式: C₃₀H₃₄B₂N₂O₃Sn
• 分子量: 610.944
• InChiKey: KJTXOJXDCPADQH-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  ([2,6-bis(dimethylamino)methyl]phenyl)Sn(Ph)[(OBPh)₂O] 、 苯硼酸 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  含SnB 4 O 6单元的N→Sn配位的锡氧烷

  摘要：

  我们在这里报告了新的N→Sn配位的氧化锡硼酸盐H [LSnB 4 O 6 R 4 ] {L = [2,6-（Me 2 NCH 2）C 6 H 3 ] -和R = Ph（6）的合成，含有非对称SnB 4 O 6单元的4-Br-Ph（7），3,5-（CF 3）2 -Ph（8）和4-CHO-Ph（9）} 。化合物6 – 9代表五价硼酸酯的新衍生物[B 5 O 6 R 4 ] -其中中心硼被锡原子取代。化合物6 - 9进行了表征通过元素分析，电喷雾电离质谱法，和NMR光谱的装置及在的情况下，6 - 8通过单晶X射线衍射分析也。Ñ→Sn的配位stannaoxidoborates的结构6 - 8由一个螺双环布置的，具有两个六元SNB 2个ö 3环在锡原子提供新stannaoxidoborate [LSnB 4 ø 6 - [R 4 ] -基序，其被补偿因为质子原子与我协调2 N组配位体L的线性和热性能的6

  DOI：

  10.1021/acs.inorgchem.5b02505
• 作为产物：
  描述：

  2-(2,6-bis((dimethylamino)methyl)phenyl)-2-phenyl-1,3,2-dioxastannetan-4-one 、 苯硼酸 以 二氯甲烷 为溶剂， 反应 24.0h， 以84%的产率得到([2,6-bis(dimethylamino)methyl]phenyl)Sn(Ph)[(OBPh)₂O]
  参考文献：
  名称：

  Synthesis and Structural Characterization of Heteroboroxines with MB₂O₃ Core (M = Sb, Bi, Sn)

  摘要：

  Reaction of organoantimony and organobismuth oxides (LSbO)(2) and (LBiO)(2) (where L is [2,6-bis(dimethylarnino)methyl]phenyl) with four equivalents of the organoboronic acids gave new heteroboroxines LM[(OBR)(2)O] 1a-2c (for M = Sb: R = Ph (1a), 4-CF3C6H4 (1b), ferrocenyl (1c); for M = Bi: R = Ph (2a), 4-CF3C6H4 (2b), and ferrocenyl (2c)). Analogously, reaction between organotin carbonate L(Ph)Sn(CO3) and two equivalents of organoboronic acids yielded compounds L(Ph)Sn[(OBR)(2)O] (where R = Ph (3a), 4-CF3C6H4 (3b), and ferrocenyl (3c)). All compounds were characterized by elemental analysis and NMR spectroscopy. Their structure was described both in solution (NMR studies) and in the solid state (X-ray diffraction analyses 1a, 1c, 2b, 3b, and 3c). All compounds contain a central MB2O3 core (M = Sb, Bi, Sn), and the bonding situation within these rings and their potential aromaticity was investigated by the help of computational methods.

  DOI：

  10.1021/ic302153s