(R,E)-ethyl 2,4,6-trimethyloct-6-enoate | 1323142-12-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (R,E)-ethyl 2,4,6-trimethyloct-6-enoate
• CAS: 1323142-12-6
• 化学式: C₁₃H₂₄O₂
• 分子量: 212.332
• InChiKey: XYKVOKQTJKHIIB-NSHBAINVSA-N

反应信息

• 作为反应物：
  描述：

  (R,E)-ethyl 2,4,6-trimethyloct-6-enoate 在 二异丁基氢化铝 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 0.42h， 生成 (R,E)-2,4,6-trimethyloct-6-en-1-ol
  参考文献：
  名称：

  Accessing the Structural Diversity of Pyridone Alkaloids: Concise Total Synthesis of Rac-Citridone A

  摘要：

  A unique route to the structural diversity of pyridone alkaloids is described based on the concept of a common synthetic strategy. Three different core structure analogues corresponding to akanthomycin, septoriamycin A, and cltridone A have been prepared by using a highly selective and novel carbocyclization reaction.

  DOI：

  10.1021/ol2017802
• 作为产物：
  描述：

  (6E)-ethyl 2,4,6-trimethylocta-2,6-dienoate 在 sodium tetrahydroborate 、 nickel(II) chloride hexahydrate 作用下， 以 乙醇 为溶剂， 生成 (R,E)-ethyl 2,4,6-trimethyloct-6-enoate
  参考文献：
  名称：

  Accessing the Structural Diversity of Pyridone Alkaloids: Concise Total Synthesis of Rac-Citridone A

  摘要：

  A unique route to the structural diversity of pyridone alkaloids is described based on the concept of a common synthetic strategy. Three different core structure analogues corresponding to akanthomycin, septoriamycin A, and cltridone A have been prepared by using a highly selective and novel carbocyclization reaction.

  DOI：

  10.1021/ol2017802