{2,3-bis[6,7-bis(dodecylthio)tetrathiafulvalen-2-ylthioethylthio]norphthalocyanine}magnesium(II) | 1336907-55-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: {2,3-bis[6,7-bis(dodecylthio)tetrathiafulvalen-2-ylthioethylthio]norphthalocyanine}magnesium(II)
• CAS: 1336907-55-1
• 化学式: C₉₂H₁₂₂MgN₈S₁₆
• 分子量: 1877.4
• InChiKey: GBOVLZBULITHKF-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  {2,3-bis[6,7-bis(dodecylthio)tetrathiafulvalen-2-ylthioethylthio]norphthalocyanine}magnesium(II) 在 溶剂黄146 作用下， 以 二氯甲烷 为溶剂， 反应 72.0h， 以86%的产率得到2,3-bis[6,7-bis(dodecylthio)tetrathiafulvalen-2-ylthioethylthio]norphthalocyanine
  参考文献：
  名称：

  The Norphthalocyanines Bearing Two TTF Units: Synthesis, Photophysical and Electrochemical Properties

  摘要：

  A magnesium norphthalocyanine (6a) was prepared by the mixed condensation of phthalonitrile in excess with the dithiomaleonitrile bearing two TTF units (5), using Mg(11) as a template. Subsequent demetalation of 6a with acetic acid gave 6b in good yield. The structures of target compounds were determined by EA, NMR and TOF MS and their electrochemical and optical properties were also studied by cyclic voltammetry and UV-vis spectroscopy.

  DOI：

  10.3987/com-11-12235
• 作为产物：
  描述：

  1,2-bis[6,7-bis(dodecylthio)tetrathiafulvalen-2-ylthioethylthio]-1,2-dicyanoethene 、 1,2-二氰基苯 在 magnesium di-n-butanolate 作用下， 以 正丁醇 为溶剂， 反应 26.0h， 以12.5%的产率得到{2,3-bis[6,7-bis(dodecylthio)tetrathiafulvalen-2-ylthioethylthio]norphthalocyanine}magnesium(II)
  参考文献：
  名称：

  The Norphthalocyanines Bearing Two TTF Units: Synthesis, Photophysical and Electrochemical Properties

  摘要：

  A magnesium norphthalocyanine (6a) was prepared by the mixed condensation of phthalonitrile in excess with the dithiomaleonitrile bearing two TTF units (5), using Mg(11) as a template. Subsequent demetalation of 6a with acetic acid gave 6b in good yield. The structures of target compounds were determined by EA, NMR and TOF MS and their electrochemical and optical properties were also studied by cyclic voltammetry and UV-vis spectroscopy.

  DOI：

  10.3987/com-11-12235