(E)-1-(4-nitrophenyl)-N-(3,4,5-trimethoxyphenyl)methanimine | 1360566-90-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-1-(4-nitrophenyl)-N-(3,4,5-trimethoxyphenyl)methanimine
• 英文别名: (E)-3,4,5-trimethoxy-N-(4-nitrobenzylidene)aniline
• CAS: 1360566-90-0
• 化学式: C₁₆H₁₆N₂O₅
• 分子量: 316.313
• InChiKey: LYBYBTFKTAPFGO-LICLKQGHSA-N

反应信息

• 作为反应物：
  描述：

  (E)-1-(4-nitrophenyl)-N-(3,4,5-trimethoxyphenyl)methanimine 在 盐酸肼 、 三乙胺 作用下， 以 甲醇 、 甲苯 为溶剂， 生成 3-hydroxy-4-(4-nitrophenyl)-1-(3,4,5-trimethoxyphenyl)azetidin-2-one
  参考文献：
  名称：

  Synthesis by diastereomeric resolution, biochemical evaluation and molecular modelling of chiral 3-hydroxyl b-lactam microtubule-targeting agents for the treatment of triple negative breast and chemoresistant colorectal cancers

  摘要：

  DOI：

  10.1016/j.bioorg.2023.106877
• 作为产物：
  描述：

  对硝基苯甲醛 、 3,4,5-三甲氧基苯胺 在 盐酸 作用下， 以 乙醇 、 水 为溶剂， 生成 (E)-1-(4-nitrophenyl)-N-(3,4,5-trimethoxyphenyl)methanimine
  参考文献：
  名称：

  Synthesis by diastereomeric resolution, biochemical evaluation and molecular modelling of chiral 3-hydroxyl b-lactam microtubule-targeting agents for the treatment of triple negative breast and chemoresistant colorectal cancers

  摘要：

  DOI：

  10.1016/j.bioorg.2023.106877

文献信息

• Method for producing organic crystal film
  申请人：SUMITOMO ELECTRIC INDUSTRIES, LTD.

  公开号：EP0562587A1

  公开（公告）日：1993-09-29

  A method for producing a crystal film of an organic compound from a molten liquid or solution of the organic compound on a substrate or between a pair of substrates, the substrate or at least one of the pair of substrates having on a part of the surface thereof a three-dimensional geometrical structure capable of controlling the direction of the crystal growth of the organic compound, and the other part of the surface thereof than the part having a three-dimensional geometrical structure being smooth. The resulting crystal film comprises a sufficiently large single crystal for application to a practical element with its orientation controlled in an arbitrarily selected direction.

  一种在基底上或一对基底之间从有机化合物的熔融液或溶液中制备有机化合物晶体膜的方法，该基底或一对基底中的至少一个在其表面的一部分具有能够控制有机化合物晶体生长方向的三维几何结构，而其表面除具有三维几何结构的部分外的另一部分是光滑的。由此产生的晶体薄膜包括一个足够大的单晶体，可应用于实际元件，其取向可控制在任意选择的方向上。
• (<i>E</i>)-4-[2-(3,4,5-Trimethoxyphenyl)ethenyl]nitrobenzene and its `bridge-flipped' analogues
  作者：Alain Collas、Frank Blockhuys

  DOI：10.1107/s0108270111030952

  日期：2011.9.15

  The solid-state structures of three push-pull acceptor-pi-donor (A-pi-D)systems differing only in the nature of the pi-spacer have been determined. (E)-1-Nitro-4-[2-(3,4,5-trimethoxyphenyl)ethenyl]benzene, C17H17NO5, (I), and its 'bridge-flipped' imine analogues, (E)-3,4,5-trimethoxy-N-(4-nitrobenzylidene)aniline, C16H16N2O5, (II), and (E)-4-nitro-N-(3,4,5-trimethoxybenzylidene)aniline, C16H16N2O5, (III), display different kinds of supramolecular networks, viz. corrugated planes, a herringbone pattern and a layered structure, respectively, all with zero overall dipole moments. Only (III) crystallizes in a noncentrosymmetric space group (P2(1)2(1)2(1)) and is, therefore, a potential material for second-harmonic generation (SHG).