potassium 5-[N-acetato(4-pyridyl)]tetrazolate | 1161844-91-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: potassium 5-[N-acetato(4-pyridyl)]tetrazolate
• 英文别名: 5-[N-acetato(4-pyridyl)]tetrazole potassium salt；potassium 5-(N-carboxymethylpyridin-4-yl)tetrazolate(1-)；K (5-[N-acetato(4-pyridyl)]tetrazole)；K(a4-ptz)
• CAS: 1161844-91-2
• 化学式: C₈H₆N₅O₂*K
• 分子量: 243.266
• InChiKey: NCVQBZXCPJWROX-UHFFFAOYSA-M

反应信息

• 作为反应物：
  描述：

  manganese(II) perchlorate hexahydrate 、 potassium 5-[N-acetato(4-pyridyl)]tetrazolate 在 HCl 作用下， 以 盐酸 为溶剂， 以44%的产率得到[Mn(5-(N-carboxymethylpyridinium-4-yl)tetrazolato(1-))2(water)2]n*2n(water)
  参考文献：
  名称：

  Three Mn(II) supramolecular coordination complexes containing carboxylate–tetrazolate ligands

  摘要：

  Three novel complexes [Mn(atza)(2)(H2O)(4)] (1), [Mn(nptza)(2)(CH3OH)(4)] (2), and [Mn(a4-ptz)(2)(H2O)(2)](n) center dot 2nH(2)O] (3) [atza = 5-aminotetrazole-1-acetato, nptza = 5-[(4-nitryl) phenyl] tetrazole-1-acetato, a4-ptz = 5-[N-acetato(4-pyridyl)] tetrazole] containing carboxylate-tetrazolate ligands have been synthesized and characterized by element analysis. X-ray crystallography shows that complexes 1 and 2 both contain mononuclear structure. The complex 3 is a 1D polymeric chain structure. Compounds 1-3 are self-assembled to form supramolecular structures through hydrogen bonds interactions. (C) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.06.011

文献信息

• A cyano-bridged Cu(<scp>i</scp>)-based organic framework coupled with the C–C bond cleavage of acetonitrile for selective and sensitive sensing of Fe³⁺ ions
  作者：Yanli Gai、Xueyan Zhao、Yan Chen、Silei Yang、Xinshu Xia、Shan Liu、Xiuyan Wan、Kecai Xiong

  DOI：10.1039/c8dt00979a

  日期：——

  A cyano-bridged Cu(I) organic framework based on [Cu6(CN)6]n was synthesized, in which cyano anions were generated in situ from the C–C bond cleavage of acetonitrile. The as-synthesized compound displays orange-red luminescence and is further proven to be a promising Fe3+ luminescent sensor with high selectivity and sensitivity.

  合成了基于[Cu 6（CN）6 ] n的氰基桥联的Cu（I）有机骨架，其中乙腈的CC键裂解原位生成氰基阴离子。合成后的化合物显示橙红色发光，并被进一步证明是具有高选择性和灵敏度的有前途的Fe 3+发光传感器。
• Three lanthanide-based coordination compounds with 5-[N-acetato(4-pyridyl)]tetrazolate
  作者：Ming-Hua He、Cheng Ji、Zhen-Dong Shen、Qiao-Yun Li、Gao-Wen Yang、Wei Shen、Qing-Guo Qiou、Xiao-Feng Shen

  DOI：10.1080/00958972.2013.778986

  日期：2013.5.1

  Reaction of 5-[N-acetato(4-pyridyl)]tetrazolate (a4-ptz) potassium salt with lanthanide(III) chlorides, produced three new coordination compounds, [Ln(a4-ptz)2(H2O)4]·Cl·2H2O (Ln = La(1), Eu(2) and Tb(3)). These compounds were characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. Complexes 1–3 displayed 1-D structures. Luminescences of 1–3 were investigated at

  5-[N-乙酰基(4-吡啶基)]四唑 (a4-ptz) 钾盐与镧系元素 (III) 氯化物反应，生成三种新的配位化合物 [Ln(a4-ptz)2(H2O)4]·Cl ·2 （Ln = La(1)、Eu(2) 和Tb(3)）。这些化合物通过元素分析、红外光谱和单晶 X 射线衍射进行了表征。复合物 1-3 显示一维结构。在室温下以固态研究 1-3 的发光。
• Synthesis and structural characterization of two novel 2D coordination polymers [PbCl(atza)]n and [PbCl(a4-ptz)]n
  作者：Qiao-Yun Li、Gao-Wen Yang、Yun-Sheng Ma、Ming-Jin Li、Yi Zhou

  DOI：10.1016/j.inoche.2008.04.002

  日期：2008.7

  Reactions of Katza (atza(-)=5-aminotetrazole-l-acetato) or Ka4-ptz (a4-ptz(-)=5-[N-acetato(4-pyridyl)ltetrazole) with PbCl2 in aqueous solution, produced two new Pb(II) compounds, [PbCl(atza)](n) (1) and [PbCl(a4-ptz)](n) (2). Both compounds were structurally characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. In I or 2, the Pb(II) centers are connected through the atzaor a4-ptz(-) bridging ligand to form a two-dimensional layered structure. The luminescence properties of 1 and 2 were investigated at room temperature in the solid state. (c) 2008 Elsevier B.V. All rights reserved.