| 1009818-62-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 1009818-62-5
• 化学式: C₄₇H₃₈CoF₂N₅O₄
• 分子量: 833.84
• InChiKey: RYWIFJGXIPWRTQ-PPIIDGFGSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [Co(diphenylglyoximato)₂Cl(pyridine)] 、 2,2'-Bisbrommethyl-4,4'-difluorbiphenyl 在 NaOH 、 NaBH₄ 作用下， 以 甲醇 、 乙醚 、 水 为溶剂， 生成 、
  参考文献：
  名称：

  Biphenyl-Bridged Dicobaloximes: Synthesis, NMR, CV, and X-Ray Study

  摘要：

  4,4'-Disubstituted biphenyl-bridged dicobaloximes, Py(L)(2)Co-CH2-Ar-CH2-Co(L)(2)Py [L = dmgH, dpgH], have been synthesized and characterized. The cobalt-bound CH2 is diastereotopic and the dmgH (Me) shows nonequivalence in the H-1 NMR. This may occur due to atropisomerism and/or restricted rotation of the C-Ph/Co-C bond. Two X-ray structures of the biphenyl-bridged dicobaloximes, reported for the first time, show no direct or indirect interaction between the two cobaloxime units [Co(dioxime)(2)Py]. The NMR spectra and X-ray structural details complement each other. Three redox processes, Collf/coll, Co-II/Co-I, and Co-IV/Co-III, are observed in the CV study. Two cobalt centers are oxidized at different potentials as two discrete units even though these are symmetrically located with respect to each other with no interaction between them.

  DOI：

  10.1021/om7009045