allyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl-(1->2)-3-O-acetyl-α-D-mannopyranoside | 612057-02-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: allyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl-(1->2)-3-O-acetyl-α-D-mannopyranoside
• CAS: 612057-02-0
• 化学式: C₄₅H₄₄O₁₆
• 分子量: 840.835
• InChiKey: DUWYCDLMMFFYON-WVTMWSDPSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.84
• 重原子数：
  61.0
• 可旋转键数：
  16.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  208.88
• 氢给体数：
  2.0
• 氢受体数：
  16.0

反应信息

• 作为反应物：
  描述：

  allyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl-(1->2)-3-O-acetyl-α-D-mannopyranoside 、 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl-(1->3)-4,6-di-O-acetyl-2-O-benzoyl-α-D-mannopyranosyl-(1->2)-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl trichloroacetamidate 、 allyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl-(1->2)-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->2)-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->6)-3,4-di-O-acetyl-α-D-mannopyranoside 生成 allyl 3,4,6-tri-O-benzoyl-α-D-mannopyranoside
  参考文献：
  名称：

  Synthesis of a mannose nonasaccharide existing in the exopolysaccharide of Cryphonectria parasitica

  摘要：

  alpha-D-Manp-(1-->2)-alpha-D-Manp-(1-->2)-alpha-D-Manp-(1-->6)[alpha-D-Manp-(1-->3)-alpha-D-Manp-(1-->2)-alpha-D-Manp-(1-->2)]+alpha-D-Manp-(1-->6)-[alpha-D-Manp-(1-->2)]+alpha-D-Manp, existing in the exopolysaccharide of Cryphonectria parasitica was synthesized as its allyl glycoside in a regio- and stereoselective manner. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0008-6215(03)00267-2
• 作为产物：
  描述：

  allyl 3-O-acetyl-4,6-O-benzylidene-α-D-mannopyranoside 在 三氟甲磺酸三甲基硅酯 作用下， 以 二氯甲烷 、 水 、 三氟乙酸 为溶剂， 反应 4.0h， 生成 allyl 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl-(1->2)-3-O-acetyl-α-D-mannopyranoside
  参考文献：
  名称：

  Synthesis of a mannose nonasaccharide existing in the exopolysaccharide of Cryphonectria parasitica

  摘要：

  alpha-D-Manp-(1-->2)-alpha-D-Manp-(1-->2)-alpha-D-Manp-(1-->6)[alpha-D-Manp-(1-->3)-alpha-D-Manp-(1-->2)-alpha-D-Manp-(1-->2)]+alpha-D-Manp-(1-->6)-[alpha-D-Manp-(1-->2)]+alpha-D-Manp, existing in the exopolysaccharide of Cryphonectria parasitica was synthesized as its allyl glycoside in a regio- and stereoselective manner. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/s0008-6215(03)00267-2