Fe 5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,5,11,13-tetraene | 39153-08-7

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: Fe 5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,5,11,13-tetraene
• CAS: 39153-08-7
• 化学式: C₁₄H₂₂FeN₄
• 分子量: 302.202
• InChiKey: ZZBCUXDCVXEVNT-DKSHHTNLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,4,8,11-Tetraazacyclotetradeca-4,6,11,13-tetraene,5,7,12,14-tetramethyl- 、 iron(II) chloride 以 叔丁醇 为溶剂， 生成 Fe 5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradeca-4,5,11,13-tetraene
  参考文献：
  名称：

  Cyclohexene oxidation with an iron cyclam-type complex encapsulated in Y-zeolite

  摘要：

  The synthesis and characterization of an iron cyclam-type complex within the cavities of a Y-zeolite is described. By comparing the performance of the heterogeneous system with the free complex in the oxidation of cyclohexene using iodosylbenzene as oxygen donor, a protection effect of the matrix over the active center was evidenced by a higher turnover and yield of products. It was possible to determine, by UV-VIS spectroscopy, that the free complex suffers molecular degradation after two hours of reaction whereas the heterogeneous catalyst remains unaltered and active after 24 hours of reaction. The main products found in the catalyzed reaction were 2-cyclohexen-1-ol, 2-cyclohexen-1-one, epoxycyclohexane and cyclohexanol.

  DOI：

  10.1016/s1381-1169(96)00340-8