[(N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediamine)Y(2,6-di-tert-butylphenoxide)(C4H8O)] | 306776-11-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediamine)Y(2,6-di-tert-butylphenoxide)(C4H8O)]
• CAS: 306776-11-4
• 化学式: C₅₀H₇₅N₂O₄Y
• 分子量: 857.062
• InChiKey: CVBMDHCRKOTGRC-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediamine 以 四氢呋喃 、 正己烷 为溶剂， 生成 [(N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediamine)Y(2,6-di-tert-butylphenoxide)(C4H8O)]
  参考文献：
  名称：

  Synthesis of highly soluble yttrium–salen complexes and the X-ray structure of N,N′-bis(3,5-di-tert-butylsalicylidene)ethylenediamine-[bis(dimethylsily)amido]yttrium

  摘要：

  N,N'-Bis(3,5-di-tert-butylsalicylidene)ethylenediamine H(2)L reacts with [Y(N(SiHMe(2))(2)}(3)(thf)(2)] in thf-hexane at ambient conditions to afford monomeric [YL{N(SiHMe(2))(2)}(thf)], the X-ray structure determination of which reveals a strongly bent coordination mode of the anionic salen derived ligand.

  DOI：

  10.1039/cc9960001385

文献信息

• Synthesis and structure of inorganic and organometallic N,N′-bis(3, 5-di-tert-butylsalicylidene)ethylenediamine yttrium complexes
  作者：William J. Evans、Cy H. Fujimoto、Joseph W. Ziller

  DOI：10.1016/s0277-5387(02)01031-8

  日期：2002.7

  The utility of the chloride precursor [(salen')Y(mu-Cl)(THF)](2), 1 (salen' = N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediamine), in preparing amide, aryloxide, and organometallic derivatives of this ancillary ligand system is described. 1 reacts with KN(SiMe3)(2) to form (salen')Y[N(SiMe3)(2)](THF), 2, but does not readily form an aryloxide derivative by reaction with LiOAr' (OAr' = 2,6-di-tert-butylphenoxide). However, (salen')Y(OAr'), 3, can be obtained by reaction of Y(OAr')(3) with H(2)salen' and crystallizes from toluene-THF as (salen')Y(OAr')(THF), 4, 4 can also be prepared by reaction of 2 with HOAr' in THE The hexafluoroacetyl-acetonate (hfac) complex, (salen')Y(hfac)(THF)(2), 5, and the organometallic derivative, (salen')Y(C5Me5), 6, can be prepared by reaction of 1 with Na(hfac) and KC5Me5, respectively. (C) 2002 Elsevier Science Ltd. All rights reserved.