[Cu(N-[2-(2-hydroxybenzylidenamino)ethyl]-4-methyl-benzene-sulfonamide)] | 1163699-45-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(N-[2-(2-hydroxybenzylidenamino)ethyl]-4-methyl-benzene-sulfonamide)]
• CAS: 1163699-45-3
• 化学式: C₃₂H₃₄CuN₄O₆S₂
• 分子量: 698.323
• InChiKey: ZRDKLFDUVQFNSS-MLQPTNSWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-[2-(2-hydroxybenzylidenamino)ethyl]-4-methyl-benzene-sulfonamide 、 copper(II) acetate monohydrate 以 四氢呋喃 为溶剂， 生成 [Cu(N-[2-(2-hydroxybenzylidenamino)ethyl]-4-methyl-benzene-sulfonamide)]
  参考文献：
  名称：

  Synthesis, crystal structures and characterization of three novel complexes with N-[2-(2-hydroxybenzylideneamino)ethyl]-4-methyl-benzene-sulfonamide as ligand

  摘要：

  Reaction of the N-tosyl-ethylenediamine and salicylaldehyde forms a new sulfonamide Schiff base N-[2-(2-hydroxybenzylideneamino) ethyl]-4-methyl-benzene-sulfonamide (H2L). Three novel complexes constructed from H2L, namely, [M(HL)(2)] center dot xH(2)O (M = Cu, x = 0 for 1, M = Ni, x = 0 for 2 and M = Zn, x = 1 for 3) have been prepared and characterized via X-ray single-crystal diffraction, elemental analysis, X- ray powder diffraction (XRPD), FT-IR, UV-Vis, TGA and photoluminescence measurements. Complex hydrogen bonds, C-H center dot center dot center dot pi and pi-pi stacking interactions lead 1-3 to present 1-D, 2-D and 3-D supramolecular architectures, respectively. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2008.10.002