| 1260436-64-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1260436-64-3
• 化学式: C₄₆H₈₆N₂O₄
• 分子量: 731.2
• InChiKey: XPMBGLCKGPXHNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.66
• 重原子数：
  52.0
• 可旋转键数：
  40.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  82.81
• 氢给体数：
  2.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  在 甲醇 、 copper(l) iodide 、 四(三苯基膦)钯 、 benzotriazol-1-yloxyl-tris-(pyrrolidino)-phosphonium hexafluorophosphate 、 potassium carbonate 、 三乙胺 作用下， 以 四氢呋喃 、 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Organogelators Based on TTF Supramolecular Assemblies: Synthesis, Characterization, and Conductive Property

  摘要：

  A closely related family of organogelators 1-2 appended one or two electroactive tetrathiafulvalene (TTF) residues, has been designed and readily synthesized by Sonogashira reactions. These compounds can gelate a variety of organic solvents in view of multiple intermolecular interactions, and compounds 2 with two TTF subunits exhibit higher gelation ability than their corresponding 1. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) investigation of the xerogels from toluene gave a visual image showing that fibrillar aggregates are entangled in three-dimensional network structures. The columnar TTF cores stacking in the fiber, evidenced by the mixed-valence states absorption at around 2000 nm in ultraviolet visible near-infrared (UV-vis-NIR) spectra, provide an efficient pathway for the electron conduction. Upon oxidized by iodine, these xerogels exhibit semiconductive behaviors with moderate levels of conductivity. Additionally, the electrical conductivity of doped-xerogels 2 is 1 order of magnitude higher than that of 1 under identical conditions.

  DOI：

  10.1021/la103686n

文献信息

• Modulating the Differentiation of Kinetically Controlled Supramolecular Polymerizations through the Alkyl Bridge Length
  作者：Cristina Naranjo、Sergio Adalid、Rafael Gómez、Luis Sánchez

  DOI：10.1002/anie.202218572

  日期：2023.3.27

  The self-assembly of N-annulated perylene bisimides (N-PBIs) has demonstrated that the ability of these units to generate different polymorphs upon supramolecular polymerization decreases as the length of the alkyl bridge separating the peripheral side chains and the central aromatic backbones decreases. The kinetically controlled supramolecular polymerization of these N-PBIs has also been investigated

  N-环状苝双酰亚胺 (N-PBI) 的自组装表明，这些单元在超分子聚合时产生不同多晶型物的能力随着分离外围侧链和中央芳族主链的烷基桥长度的减少而降低。还研究了这些 N-PBI 的动力学控制超分子聚合。