bis-(2-diethylphosphino-ethyl)sulfide | 847043-59-8

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: bis-(2-diethylphosphino-ethyl)sulfide
• 英文别名: 2-(2-Diethylphosphanylethylsulfanyl)ethyl-diethylphosphane
• CAS: 847043-59-8
• 化学式: C₁₂H₂₈P₂S
• 分子量: 266.368
• InChiKey: LQWOOIFSLKCDQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  trichlorotris(tetrahydrofuran)chromium(III) 、 bis-(2-diethylphosphino-ethyl)sulfide 以 四氢呋喃 为溶剂， 生成 2-(2-Diethylphosphanylethylsulfanyl)ethyl-diethylphosphane;trichlorochromium
  参考文献：
  名称：

  10.1021/om049168-

  摘要：

  DOI：

  10.1021/om049168-

文献信息

• Methods of preparation of an olefin oligomerization catalyst
  申请人：Knudsen D. Ronald

  公开号：US20050187391A1

  公开（公告）日：2005-08-25

  A method of making a catalyst for use in oligomerizing an olefin comprising a chromium-containing compound, a pyrrole-containing compound, a metal alkyl, a halide-containing compound, and optionally a solvent, the method comprising contacting a composition comprising the chromium-containing compound and a composition comprising the metal alkyl, wherein the composition comprising the chromium-containing compound is added to the composition comprising the metal alkyl.

  制备用于寡聚烯烃的催化剂的方法包括含铬化合物、含吡咯化合物、金属烷基、含卤化合物和可选的溶剂，该方法包括将含铬化合物的组合物与含金属烷基的组合物接触，其中含铬化合物的组合物被添加到含金属烷基的组合物中。
• Trimerisation and oligomerisation of olefins using a chromium based catalyst
  申请人：Dixon Thomas John

  公开号：US20050131262A1

  公开（公告）日：2005-06-16

  The invention provides a mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms, of which at least one heteroatom is sulfur and at least 2 heteroatoms are not the same. The invention also provides a multidentate mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms of which at least one is a sulfur atom. The ligand may also contain, in addition to sulfur, at least one nitrogen or phosphorous heteroatom.

  本发明提供了一种用于烯烃寡聚催化剂的混合杂原子配体，该配体包括至少三个杂原子，其中至少一个杂原子是硫，至少有2个杂原子不相同。本发明还提供了一种多齿混合杂原子配体，用于烯烃寡聚催化剂，该配体包括至少三个杂原子，其中至少一个是硫原子。该配体还可以包含除硫外，至少一个氮或磷杂原子。
• TRIMERISATION AND OLIGOMERISATION OF OLEFINS USING A CHROMIUM BASED CATALYST
  申请人：Dixon John Thomas

  公开号：US20080200744A1

  公开（公告）日：2008-08-21

  The invention provides a mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms, of which at least one heteroatom is sulfur and at least two heteroatoms are not the same. The invention also provides a multidentate mixed heteroatomic ligand for an oligomerisation of olefins catalyst, which ligand includes at least three heteroatoms of which at least one is a sulfur atom. The ligand may also contain, in addition to sulfur, at least one nitrogen or phosphorous heteroatom.

  本发明提供了用于烯烃寡聚催化剂的混合杂原子配体，该配体包括至少三个杂原子，其中至少一个杂原子是硫，至少两个杂原子不相同。本发明还提供了用于烯烃寡聚催化剂的多齿混合杂原子配体，该配体包括至少三个杂原子，其中至少一个是硫原子。配体还可以除硫外，包含至少一个氮或磷杂原子。
• METHODS OF PREPARATION OF AN OLEFIN OLIGOMERIZATION CATALYST
  申请人：CHEVRON PHILLIPS CHEMICAL COMPANY LP

  公开号：EP1716089B1

  公开（公告）日：2015-04-08
• JP2005533872A
  申请人：——

  公开号：JP2005533872A

  公开（公告）日：2005-11-10