3-bromo-1,6-bis(4-methylphenyl)pyrene | 908011-88-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 3-bromo-1,6-bis(4-methylphenyl)pyrene
• 英文别名: 3-Bromo-1,6-bis(4-methylphenyl)pyrene
• CAS: 908011-88-1
• 化学式: C₃₀H₂₁Br
• 分子量: 461.401
• InChiKey: JWHJQTXGCAPMKL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.7
• 重原子数：
  31
• 可旋转键数：
  2
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,6-bis(4-methylphenyl)pyrene 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 N-甲基乙酰胺 、 二氯甲烷 、 水 为溶剂， 生成 3-bromo-1,6-bis(4-methylphenyl)pyrene
  参考文献：
  名称：

  Light-emitting device material and light-emitting device

  摘要：

  一种含有式（1）的芘化合物的发光器件材料和发光器件。在式（1）中，R1到R18相同或不同，可从氢、烷基、环烷基、杂环烷基、烯基、环烯基、炔基、烷氧基、烷硫基、芳基醚、芳硫醚、芳基、杂芳基、卤素、羰基、羧基、氧羰基、氨基、膦氧化物和硅基中选择；R1到R18中相邻的取代基可能结合在一起形成环；n代表1至3的整数；X为—O—、—S—或—NR19—；R19从氢、烷基、环烷基、杂环烷基、烯基、环烯基、炔基、芳基、杂芳基或氨基中选择；R19可以与R11或R18结合形成环；Y为单键、芳基或杂芳基；R1到R10中的n个取代基和R11到R19中的任意一个用于与Y连接。

  公开号：

  US20090096356A1

文献信息

• MATERIAL FOR LIGHT-EMITTING ELEMENT AND LIGHT EMITTING ELEMENT
  申请人：Sugimoto Kazunori

  公开号：US20090066245A1

  公开（公告）日：2009-03-12

  The present invention is a light-emitting device material characterized by containing a pyrene compound represented by the following general formula (1): wherein R1 to R10 are specific functional groups, provided that at least one of the R1 to R10 is a substituent represented by the following general formula (2): wherein R11 to R14 are specific functional groups, provided that any one of the R11 to R14 is used for a single bond with a pyrene skeleton; X1 is a group represented by the following general formula (3): wherein R15 is a specific functional group; and Y1 to Y4 is selected from among a nitrogen atom and a carbon atom, provided that at least one of the Y1 to Y4 is a nitrogen atom and at least one thereof is a carbon atom, and no substituents exist on the nitrogen atom in the case of the nitrogen atom. This material provides a light-emitting device having high luminous efficiency and excellent durability.

  本发明是一种发光装置材料，其特征在于包含以下通式（1）所表示的芘化合物，其中R1至R10是特定的功能基团，但至少其中之一是以下通式（2）所表示的取代基：其中R11至R14是特定的功能基团，但其中任意一个用于与芘骨架形成单键；X1是以下通式（3）所表示的基团：其中R15是特定的功能基团；Y1至Y4从氮原子和碳原子中选择，但至少一个是氮原子，且其中至少一个是碳原子，在氮原子的情况下不存在取代基。该材料提供了具有高发光效率和优异耐久性的发光装置。
• Material for light-emitting element and light emitting element
  申请人：Toray Industries, Inc.

  公开号：US07901794B2

  公开（公告）日：2011-03-08

  The present invention is a light-emitting device material characterized by containing a pyrene compound represented by the following general formula (1): wherein R1 to R10 are specific functional groups, provided that at least one of the R1 to R10 is a substituent represented by the following general formula (2): wherein R11 to R14 are specific functional groups, provided that any one of the R11 to R14 is used for a single bond with a pyrene skeleton; X1 is a group represented by the following general formula (3): wherein R15 is a specific functional group; and Y1 to Y4 is selected from among a nitrogen atom and a carbon atom, provided that at least one of the Y1 to Y4 is a nitrogen atom and at least one thereof is a carbon atom, and no substituents exist on the nitrogen atom in the case of the nitrogen atom. This material provides a light-emitting device having high luminous efficiency and excellent durability.

  本发明是一种发光装置材料，其特征在于包含以下通式（1）所表示的芘化合物，其中R1至R10是特定的功能基团，但至少其中之一是以下通式（2）所表示的取代基：其中R11至R14是特定的功能基团，但其中任意一个用于与芘骨架形成单键；X1是以下通式（3）所表示的基团：其中R15是特定的功能基团；Y1至Y4从氮原子和碳原子中选择，但至少其中之一是氮原子，且至少有一个是碳原子，在氮原子情况下不存在取代基。该材料提供具有高发光效率和优异耐久性的发光装置。
• Material for light-emitting device and light-emitting device
  申请人：Nagao Kazumasa

  公开号：US20100163852A1

  公开（公告）日：2010-07-01

  The present invention provides a light emitting device material which enables a light emitting device having high efficiency and excellent chromatic purity and durability using a light emitting device material containing a pyrene compound represented by formula (1), wherein any one of R 1 to R 10 is a group represented by formula (2), or 1 to 4 substituents is/are group(s) represented by formula (3), and a light emitting device using the same.

  本发明提供了一种发光器件材料，该材料包含由式（1）表示的芘化合物的发光器件材料，其中R1至R10中的任意一个是由式（2）表示的基团，或者1至4个取代基是由式（3）表示的基团，从而使得使用该发光器件材料的发光器件具有高效率、优异的色纯度和耐久性。
• LIGHT-EMITTING DEVICE MATERIAL AND LIGHT-EMITTING DEVICE
  申请人：Toray Industries, Inc.

  公开号：US20140061629A1

  公开（公告）日：2014-03-06

  A light emitting device material containing a pyrene compound of general formula (1) and a light emitting device. In formula (1), R 1 to R 18 are the same or different and are selected from hydrogen, alkyl, cycloalkyl, heterocyclic, alkenyl, cycloalkenyl, alkynyl, alkoxy, alkylthio, arylether, arylthioether, aryl, heteroaryl, halogen, carbonyl, a carboxyl, oxycarbonyl, carbamoyl, amino, phosphine oxide and silyl; adjacent substituents among R 1 to R 18 may be combined with each other to form a ring; n is an integer of 1 to 3; X is —O—, —S— or —NR 19 —; R 19 is hydrogen, alkyl, cycloalkyl, heterocyclic, alkenyl, cycloalkenyl, alkynyl, aryl, heteroaryl or amino; R 19 may be combined with R 11 or R 18 to form a ring; Y is a single bond, arylene or heteroarylene; and n substituents among R 1 to R 10 and any one of R 11 to R 19 are used for linkage with Y

  一种含有通式（1）的芘化合物的发光装置材料和发光装置。在式（1）中，R1至R18相同或不同，可选择自氢、烷基、环烷基、杂环、烯基、环烯基、炔基、烷氧基、烷硫基、芳基醚、芳硫醚、芳基、杂芳基、卤素、羰基、羧基、氧羰基、氨基、磷氧化物和硅烷中；相邻的R1至R18取代基可以结合形成环；n是1到3的整数；X是—O—、—S—或—NR19—；R19是氢、烷基、环烷基、杂环、烯基、环烯基、炔基、芳基、杂芳基或氨基；R19可以与R11或R18结合形成环；Y是单键、芳基或杂芳基；R1至R10中的n个取代基和R11至R19中的任意一个取代基用于与Y连接。
• Light emitting device material and light emitting device
  申请人：Toray Industries, Inc.

  公开号：EP2463351A2

  公开（公告）日：2012-06-13

  The present invention relates to a light emitting device material containing a pyrene compound represented by the general formula (1): wherein R1 to R18 may be the same or different and represent a group selected from hydrogen, an alkyl group, a cycloalkyl group, a heterocyclic group, an alkenyl group, a cycloalkenyl group, an alkynyl group, an alkoxy group, an alkylthio group, an arylether group, an arylthioether group, an aryl group, a heteroaryl group, a halogen, a carbonyl group, a carboxyl group, an oxycarbonyl group, a carbamoyl group, an amino group, a phosphine oxide group and a silyl group; adjacent substituents among R1 to R18 may be combined with each other to form a ring; n represents an integer of 1 to 3; X represents -S-; Y represents an arylene group or a heteroarylene group; and n substituents among R1 to R10 and any one of R11 to R19 are used for linkage with Y.

  本发明涉及一种含有通式（1）代表的芘化合物的发光器件材料： 烷硫基、芳基醚基、芳基硫醚基、芳基、杂芳基、卤素、羰基、羧基、氧羰基、氨基甲酰基、氨基、氧化膦基和硅烷基；R1 至 R18 中的相邻取代基可相互结合形成一个环；n 代表 1 至 3 的整数；X 代表-S-；Y 代表芳基或杂芳基；R1 至 R10 中的 n 个取代基和 R11 至 R19 中的任一个取代基用于与 Y 连接。