2-[2-(2-Aminoethylamino)ethyliminomethyl]-6-[[bis(pyridin-2-ylmethyl)amino]methyl]-4-methylphenol | 516507-50-9

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 2-[2-(2-Aminoethylamino)ethyliminomethyl]-6-[[bis(pyridin-2-ylmethyl)amino]methyl]-4-methylphenol
• CAS: 516507-50-9
• 化学式: C₂₅H₃₂N₆O
• 分子量: 432.569
• InChiKey: ORKIIERAGRUSCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  32
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  99.7
• 氢给体数：
  3
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  sodium hexaflorophosphate 、 2-[2-(2-Aminoethylamino)ethyliminomethyl]-6-[[bis(pyridin-2-ylmethyl)amino]methyl]-4-methylphenol 、 nickel(II) acetate tetrahydrate 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Di- and tetra-nuclear nickel(II) complexes of an unsymmetric compartmental ligand bearing a terdentate linear arm and a terdentate dipodal arm

  摘要：

  The unsymmetric compartmental proligand HLO reacts with Ni(OAc)(2) and NaSCN, to give the homodinuclear complex [Ni-2(L-O)(AcO)(SCN)(2)] (3), whereas the unsymmetric compartmental proligand HLN reacts with Ni(OAc)(2) in the presence of either [BF4](-) or [PF6](-) counteranions to give the tetranuclear complexes [Ni-4(L-1)(2)(OAc)(4)][X](2), (4a, X = PF6; 4b, X = BF4), in which ligand modification has occurred such that the iminic pendant arm of the proligand has been converted into an amidic pendant arm. The crystal structures of 3 and (4b)(2).3CH(3)OH.2H(2)O are reported. (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(02)01309-8