trigylycidyl isocyanurate acrylate | 38817-87-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: trigylycidyl isocyanurate acrylate
• 英文别名: acrylic acid 2,2',2''-trihydroxy-3,3',3''-(2,4,6-trioxo-[1,3,5]triazinane-1,3,5-triyl)-tripropyl ester；[3-[3,5-Bis(2-hydroxy-3-prop-2-enoyloxypropyl)-2,4,6-trioxo-1,3,5-triazinan-1-yl]-2-hydroxypropyl] prop-2-enoate
• CAS: 38817-87-7
• 化学式: C₂₁H₂₇N₃O₁₂
• 分子量: 513.458
• InChiKey: XDTFHFYLINMJNZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1
• 重原子数：
  36
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  201
• 氢给体数：
  3
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  丙烯酸 、 1,3,5-三缩水甘油-S-三嗪三酮 在 4-甲氧基苯酚 、 三乙胺 作用下， 以 1,4-二氧六环 为溶剂， 反应 3.0h， 生成 trigylycidyl isocyanurate acrylate
  参考文献：
  名称：

  基于紫外光固化阻燃涂料的棉纺织品的阻燃和热降解

  摘要：

  阻燃涂料是通过紫外线固化技术使用磷酸三（丙烯酰氧乙基）酯（TAEP）和异氰脲酸三缩水甘油酯丙烯酸酯（TGICA）制备的。FTIR-ATR 光谱和扫描电子显微镜 (SEM) 的结果表明，阻燃涂层成功地涂覆在棉织物表面。通过微量燃烧量热仪（MCC）和极限氧指数（LOI）研究了处理过的织物的阻燃性。与未处理的棉相比，棉包覆的阻燃涂料具有较低的峰值放热率（PHRR）、放热能力（HRC）、总燃烧热（THC）和较高的 LOI 值。TGA 测试结果表明，阻燃涂层降低了处理织物的分解温度。通过实时 FTIR 分析和热重分析/红外光谱 (TGA-IR) 监测棉花的热分解。增强的阻燃作用可能是由 TAEP 结构的热分解引起的，产生酸性中间体，可与织物反应以改变其热分解过程。

  DOI：

  10.1016/j.tca.2010.11.014

文献信息

• Crosslinkable compound-containing photocurable stepped substrate-coating composition
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US11454889B2

  公开（公告）日：2022-09-27

  A stepped substrate-coating composition for forming a coating film having filling property of a pattern and flattening property including a compound (E) having a partial structure (I) and a partial structure (II) having a hydroxy group formed by a reaction of an epoxy group with a proton-generating compound, a solvent (F), and a crosslinkable compound (H), wherein the partial structure (I) is from Formulae (1-1) to (1-5) or including a partial structure of Formula (1-6) combined with a partial structure of Formula (1-7) or (1-8), and the partial structure (II) is of the following Formula (2-1) or (2-2), wherein the compound (E) contains the epoxy and hydroxy group at a molar ratio (epoxy group)/(hydroxy group) of 0 or more and 0.5 or less, and contains the partial structure (II) so the molar ratio (partial structure (II))/(partial structure (I)+partial structure (II)) is 0.01 or more and 0.8 or less.

  一种用于形成具有图案填充特性和平整特性的涂膜的阶梯基材-涂层组合物，包括具有部分结构（I）的化合物（E）和具有由环氧基团与质子生成化合物反应形成的羟基的部分结构（II）、溶剂（F）和可交联化合物（H）、其中部分结构(I)为式(1-1)至(1-5)或包括式(1-6)的部分结构与式(1-7)或(1-8)的部分结构相结合，部分结构(II)为下式(2-1)或(2-2)，其中化合物(E)含有环氧基和羟基，其摩尔比(环氧基)/(羟基)为0或以上和0.5或以下，并含有部分结构(II)，因此摩尔比(部分结构(II))/(部分结构(I)+部分结构(II))为0.01或以上和0.8或以下。
• UV-CURABLE EPOXY ACRYLATES
  申请人：Huntsman Advanced Materials (Switzerland) GmbH

  公开号：EP1572814B1

  公开（公告）日：2010-01-27
• CROSSLINKABLE COMPOUND-CONTAINING PHOTOCURABLE STEPPED SUBSTRATE-COATING COMPOSITION
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US20200225585A1

  公开（公告）日：2020-07-16

  A stepped substrate-coating composition for forming a coating film having filling property of a pattern and flattening property including a compound (E) having a partial structure (I) and a partial structure (II) having a hydroxy group formed by a reaction of an epoxy group with a proton-generating compound, a solvent (F), and a crosslinkable compound (H), wherein the partial structure (I) is from Formulae (1-1) to (1-5) or including a partial structure of Formula (1-6) combined with a partial structure of Formula (1-7) or (1-8), and the partial structure (II) is of the following Formula (2-1) or (2-2), wherein the compound (E) contains the epoxy and hydroxy group at a molar ratio (epoxy group)/(hydroxy group) of 0 or more and 0.5 or less, and contains the partial structure (II) so the molar ratio (partial structure (II))/(partial structure (I)+partial structure (II)) is 0.01 or more and 0.8 or less.
• STEPPED SUBSTRATE COATING COMPOSITION CONTAINING COMPOUND HAVING CURABLE FUNCTIONAL GROUP
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US20210024773A1

  公开（公告）日：2021-01-28

  A stepped substrate coating composition for forming a coating film having planarity on a substrate, including: a main agent and a solvent, the main agent containing a compound (A), a compound (B), or a mixture thereof, the compound (A) having a partial structure Formula (A-1) or (A-2): and the compound (B) having at least one partial structure selected from Formulae (B-1)-(B-5), or having a partial structure including a combination of a partial structure of Formula (B-6) and a partial structure of Formula (B-7) or (B-8): where the composition is cured by photoirradiation or by heating at 30° C.-300° C.; and the amount of the main agent in the solid content of the composition is 95%-100% by mass.
• Flame retardancy and thermal degradation of cotton textiles based on UV-curable flame retardant coatings
  作者：Weiyi Xing、Ganxin Jie、Lei Song、Shuang Hu、Xiaoqi Lv、Xin Wang、Yuan Hu

  DOI：10.1016/j.tca.2010.11.014

  日期：2011.1

  The flame retardant coatings were prepared through UV-curable technique using tri(acryloyloxyethyl) phosphate (TAEP) and triglycidyl isocyanurate acrylate (TGICA). Results from FTIR-ATR spectroscopy and scanning electron microscopy (SEM) showed that flame retardant coatings were successfully coated onto the surface of cotton fabrics. The flame retardancy of the treated fabrics was studied by Micro-scale

  阻燃涂料是通过紫外线固化技术使用磷酸三（丙烯酰氧乙基）酯（TAEP）和异氰脲酸三缩水甘油酯丙烯酸酯（TGICA）制备的。FTIR-ATR 光谱和扫描电子显微镜 (SEM) 的结果表明，阻燃涂层成功地涂覆在棉织物表面。通过微量燃烧量热仪（MCC）和极限氧指数（LOI）研究了处理过的织物的阻燃性。与未处理的棉相比，棉包覆的阻燃涂料具有较低的峰值放热率（PHRR）、放热能力（HRC）、总燃烧热（THC）和较高的 LOI 值。TGA 测试结果表明，阻燃涂层降低了处理织物的分解温度。通过实时 FTIR 分析和热重分析/红外光谱 (TGA-IR) 监测棉花的热分解。增强的阻燃作用可能是由 TAEP 结构的热分解引起的，产生酸性中间体，可与织物反应以改变其热分解过程。