Vinyl-2,4-xylenyl ether | 123316-10-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Vinyl-2,4-xylenyl ether
• 英文别名: 1-Ethenoxy-2,4-dimethylbenzene
• CAS: 123316-10-9
• 化学式: C₁₀H₁₂O
• 分子量: 148.205
• InChiKey: VTRYNSCEPFJVQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  一氧化碳 、 Vinyl-2,4-xylenyl ether 在 铑 氢气 作用下， 生成 2-(2,4-Dimethyl-phenoxy)-propionaldehyde
  参考文献：
  名称：

  FR2213928

  摘要：

  公开号：

文献信息

• [2 + 2] Cycloaddition of <i>o</i>-Carboryne with Vinyl Ethers: Synthesis of Carborane-Fused Cyclobutanes
  作者：Jie Zhang、Zuowei Xie

  DOI：10.1021/acs.organomet.0c00163

  日期：2020.12.14

  precursor, o-carboryne undergoes an efficient [2 + 2] cycloaddition with a large variety of vinyl ethers at room temperature to give a series of carborane-fused cyclobutanes in very good to high isolated yields. This reaction is compatible with many functional groups and has a very broad substrate scope ranging from alkyl- to aryl- and to silyl-substituted vinyl ethers. A stepwise reaction mechanism is proposed

  邻-碳硼炔（1,2-脱氢-邻-碳硼烷）是用于合成各种经碳硼烷官能化的分子的非常有用的合成子。使用1-锂-2- OTf- ö -C 2乙10 ħ 10作为前体，Ô-卡波炔在室温下与多种乙烯基醚进行有效的[2 + 2]环加成反应，以非常好的或高的分离产率得到一系列碳硼烷稠合的环丁烷。该反应与许多官能团相容，并且具有非常宽的底物范围，范围从烷基到芳基以及甲硅烷基取代的乙烯基醚。在控制实验的基础上，提出了一种逐步反应机理，并得到了DFT计算的支持。所有新化合物均已通过1 H，13 C和11 B NMR光谱以及HRMS光谱进行了全面表征。一些通过单晶X射线分析进一步证实。
• CURABLE COMPOSITION, CURED PRODUCT, AND COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20220177641A1

  公开（公告）日：2022-06-09

  a curable composition that gives a cured product exhibiting a high refractive index and a surface without defects such as roughness or cracks, a cured product of the composition, and a compound that may be blended to the composition. In a curable composition including a triazine compound having three aromatic-ring-containing groups each bonded to the triazine ring via an amino group, an aromatic-ring-containing group having a specific structure having a radically polymerizable group-containing group or a cationically polymerizable group-containing group is used as at least one of the three aromatic-ring-containing groups bonded to the triazine ring in the triazine compound mentioned above.

  一种可治愈的组合物，可产生具有高折射率和表面无缺陷（如粗糙或裂纹）的固化产品，该组合物的固化产品以及可混合到该组合物中的化合物。在包括三嗪化合物的可固化组合物中，每个含有芳香环的基团均通过氨基与三嗪环结合，具有特定结构的含芳香环基团具有具有自由基聚合基团或阴离子聚合基团的群组，至少用作上述三嗪化合物中与三嗪环结合的三个芳香环含基团之一。
• Coating varnish composition and antifouling coating composition
  申请人：Hitachi Chemical Co., Ltd.

  公开号：EP0711813A2

  公开（公告）日：1996-05-15

  A coating varnish composition comprising a biodegradable polymer (A) comprising one or more kinds of constituent units (b) represented by the general formula (I), (II) or (III) and one or more other kinds of constituent units (a) capable of imparting bio-degradability: wherein in the formula (I), R¹ and R are independently a hydrogen atom, a chlorine atom, a bromine atom, a methyl group, an ethyl group or a phenyl group; in the formula (II), R³ and R⁴ are independently a hydrogen atom, a chlorine atom, a bromine atom, or a substituted or unsubstituted methyl or ethyl group; in the formula (III), R⁵ and R⁶ are independently a hydrogen atom, a methyl group or an ethyl group, and R⁷ is a straight, branched or cyclic alkyl group, an aryl group, a heterocyclic group or an aralkyl group, which may have one or more substituents.

  一种涂料清漆组合物，包含一种可生物降解聚合物 (A)，该聚合物包含一种或多种由通式 (I)、(II) 或 (III) 表示的组成单元 (b) 和一种或多种可赋予生物降解性的其他组成单元 (a)： 其中，在式 (I) 中，R¹ 和 R 独立地为氢原子、氯原子、溴原子、甲基、乙基或苯基；在式 (II) 中，R³ 和 R⁴ 独立地为氢原子、氯原子、溴原子或取代或未取代的甲基或乙基；在式 (III) 中，R⁵ 和 R⁶ 独立地是氢原子、甲基或乙基，R⁷ 是直链、支链或环状烷基、芳基、杂环基或芳烷基，它们可以有一个或多个取代基。
• Curable composition, adhesive, method of producing fiber-reinforced composite material, and fiber-reinforced composite material
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：EP2930200A1

  公开（公告）日：2015-10-14

  A curable composition is obtained by blending a polymerizable compound (A) having predetermined kinds of polymerizable functional groups, a reactive compound (B) having predetermined kinds of reactive functional groups, a compound (C) which is an imidazolyl group-containing compound having a predetermined structure, and a compound (D) which is an oxime compound or an oxime ester compound having a predetermined structure.

  将具有预定种类可聚合官能团的可聚合化合物 (A)、具有预定种类活性官能团的活性化合物 (B)、具有预定结构的含咪唑基化合物 (C) 和具有预定结构的肟化合物或肟酯化合物 (D) 混合在一起，可得到一种可固化组合物。
• Curable composition, cured product of the curable composition, and method of producing a cured product using the curable composition
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US10479879B2

  公开（公告）日：2019-11-19

  A cationically polymerizable curable composition comprising a compound having a vinyloxy group bonded to an aromatic group which is easily cured upon light exposure and/or heating, a cured product of the curable composition, and a method of producing a cured product using the curable composition. In a cationically polymerizable curable composition that includes a compound having a vinyloxy group bonded to an aromatic group, a sulfonium salt having a specific structure is used as a curing agent. A cured product is produced by shaping the curable composition into a predetermined shape, and subjecting the shaped curable composition to light exposure and/or heating.

  一种阳离子可聚合固化组合物，其中包含一种具有与芳香基键合的乙烯氧基的化合物，该化合物在光照和/或加热时容易固化；一种固化组合物的固化产品；以及一种使用该固化组合物生产固化产品的方法。在阳离子可聚合固化组合物中，包括一种具有与芳香基键合的乙烯氧基的化合物，具有特定结构的锍盐被用作固化剂。通过将固化组合物塑造成预定形状，并将塑造好的固化组合物进行光照和/或加热，即可制成固化产品。