1-Amino-4-mesidino-2-(4-tert-butyl-phenoxy)-anthrachinon | 17095-28-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1-Amino-4-mesidino-2-(4-tert-butyl-phenoxy)-anthrachinon
• 英文别名: 1-Amino-2-(4-tert-butylphenoxy)-4-(2,4,6-trimethylanilino)anthracene-9,10-dione
• CAS: 17095-28-2
• 化学式: C₃₃H₃₂N₂O₃
• 分子量: 504.629
• InChiKey: BLBRTBATKAVQCG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.1
• 重原子数：
  38
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  81.4
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1-Amino-4-mesidino-2-(4-tert-butyl-phenoxy)-anthrachinon 在 sodium azide 、 亚硝酸正戊酯 、 溶剂黄146 作用下， 以 N,N-二甲基甲酰胺 、 甲苯 、 苯 为溶剂， 反应 3.75h， 生成 2-tert-Butyl-7-(2,4,6-trimethyl-phenylamino)-14H-naphtho[2,3-a]phenoxazine-8,13-dione
  参考文献：
  名称：

  Gornostaev, L. M.; Levdanskii, V. A., Journal of Organic Chemistry USSR (English Translation), 1980, vol. 16, p. 1884 - 1890

  摘要：

  DOI：

文献信息

• BLUE COLOUR FILTERS WITH ENHANCED CONTRAST
  申请人：Ciba Holding Inc.

  公开号：EP1984457A2

  公开（公告）日：2008-10-29
• Blue Colour Filters with Enhanced Contrast
  申请人：Hall-Goulle Véronique

  公开号：US20100227199A1

  公开（公告）日：2010-09-09

  The invention relates to a process for enhancing the contrast of colour filters comprising α copper phthalocyanine or ε copper phthalocyanine, wherein a 1,4-diamino-anthraquinone dye or 1,9-annellated derivative thereof, of which the most bathochromic solution absorption peak in the visible spectrum is at from 575 to 615 nm, preferably at from 585 to 605 nm (as compared with around 630 nm for usual 1,4-diamino-anthraquinone dyes or 1,9-annellated derivatives thereof) is used in combination with α copper phthalocyanine or ε copper phthalocyanine. Also claimed are colour filters comprising such 1,4-diamino-anthraquinone dyes or 1,9-annellated derivatives thereof, as well as a novel compound of Formula (II), wherein R 16 is halogen, phenyl, benzyl or C 1 -C 8 alkyl and R 17 is H, R 16 is H and R 17 is C 1 -C 8 alkyl, or R 16 and R 17 are both H; R 18 is H, halogen, C 1 -C 8 alkyl or SO 2 NR 13 R 14 ; R 19 , R 20 and R 21 are each independently from the others halogen or C 1 -C 8 alkyl; and R 22 is independently from R 18 SO 2 NR 13 R 14 , with the proviso that at least one of R 18 and R 22 is SO 2 NR 13 R 14 , and two radicals of Formula (II) can optionally be linked together via a direct bond or a group —O—, —S—, —NR 14 —, —CO—, —CO 2 —, —CONR 14 — or —CO 2 — connecting together each a substituent R 16 , R 17 , R 18 , R 19 , R 20 , R 21 and R 11 from both radicals of formula (II).
• US8148358B2
  申请人：——

  公开号：US8148358B2

  公开（公告）日：2012-04-03
• [EN] BLUE COLOUR FILTERS WITH ENHANCED CONTRAST<br/>[FR] FILTRES DE COULEUR BLEUE À CONTRASTE AMÉLIORÉ
  申请人：CIBA SC HOLDING AG

  公开号：WO2007093536A2

  公开（公告）日：2007-08-23

  [EN] The invention relates to a process for enhancing the contrast of colour filters comprising a copper phthalocyanine or e copper phthalocyanine, wherein a 1,4-diamino-anthraquinone dye or 1,9-annellated derivative thereof, of which the most bathochromic solution absorption peak in the visible spectrum is at from 575 to 615 nm, preferably at from 585 to 605 nm (as compared with around 630 nm for usual 1,4-diamino-anthraquinone dyes or 1,9-annellated derivatives thereof) is used in combination with a copper phthalocyanine or e copper phthalocyanine. Also claimed are colour filters comprising such 1,4-diamino-anthraquinone dyes or 1,9-annellated derivatives thereof, as well as a novel compound of formula (II), wherein R₁₆ is halogen, phenyl, benzyl or C₁-C₈alkyl and R₁₇ is H, R₁₆ is H and R₁₇ is C₁-C₈alkyl, or R₁₆ and R₁₇ are both H; R₁₈ is H, halogen, C₁-C₈alkyl or SO₂NR₁₃R₁₄; R₁₉, R_2O and R₂₁ are each independently from the others halogen or C₁-C₈alkyl; and R₂₂ is independently from R₁₈ SO₂NR₁₃R₁₄, with the proviso that at least one of R₁₈ and R₂₂ is SO₂NR₁₃R₁₄, and two radicals of formula (II) can optionally be linked together via a direct bond or a group -O-, -S-, -NR₁₄-, -CO-, -CO₂-, -CONR₁₄- or -CO₂- connecting together each a substituent R₁₆, R₁₇, R₁₈, R₁₉, R₂₀, R₂₁ and R₁₁ from both radicals of formula (II).
  [FR] L'invention porte sur un procédé améliorant le contraste de filtres de couleur, selon lequel un colorant de 1,4-diamino-anthraquinone ou son dérivé 1,9 recuit (dont le pic d'absorption de sa solution la plus bathochrome dans le spectre visible va de 575 à 615 nm ou mieux de 585 à 605 nm, comparé à environ 630 nm pour les colorants de 1,4-diamino-anthraquinone) est utilisé en combinaison avec de la phthalocyanine a de cuivre ou de la phthalocyanine e de cuivre. L'invention porte également sur des filtres de couleur comprenant des colorants de 1,4-diamino-anthraquinone dyes ou leurs dérivés 1,9 recuits, et sur de nouveaux composés de formule (II) dans laquelle: R16 est halogène, phényle, benzyle ou C1-C8alkyle et R17 est H, R16 est H et R17 est C1-C8alkyle, ou R16 et R17 sont tous deux H; R18 est H, halogène, C1-C8alkyle ou SO2NR13R14; R19, R2O et R21 sont chacun indépendamment des autres halogène ou C1-C8alkyle; et R22 est SO2NR13R14 indépendamment de R18, sous réserve, qu'au moins l'un de R18 et R22 soit SO2NR13R14, et que deux radicaux de formule (II) puissent facultativement être liés ensemble par une liaison directe ou un groupe -O-, -S-, -NR14-, -CO-, -CO2-, -CONR14- ou -CO2- liant ensemble chacun un substituant R16, R17, R18, R19, R20, R21 et R11 des deux radicaux de formule (II).