3-[7-fluoro-2H-1,4-benzoxazin-3(4H)-on-6-yl]-5-isopropylidene-1,3-oxazolidine-2,4-dione | 124869-48-3

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 3-[7-fluoro-2H-1,4-benzoxazin-3(4H)-on-6-yl]-5-isopropylidene-1,3-oxazolidine-2,4-dione
• 英文别名: 3-(7-fluoro-3-oxo-4H-1,4-benzoxazin-6-yl)-5-propan-2-ylidene-1,3-oxazolidine-2,4-dione
• CAS: 124869-48-3
• 化学式: C₁₄H₁₁FN₂O₅
• 分子量: 306.25
• InChiKey: ITTJVPJJLTUCOX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  84.9
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  3-[7-fluoro-2H-1,4-benzoxazin-3(4H)-on-6-yl]-5-isopropylidene-1,3-oxazolidine-2,4-dione 生成 3-(7-Fluoro-3-oxo-4-prop-2-enyl-1,4-benzoxazin-6-yl)-5-propan-2-ylidene-1,3-oxazolidine-2,4-dione
  参考文献：
  名称：

  XIRAI, KEHNDZI;FUDZITA, ATSUKO;SATO, XIROSI;XIROSA, XIROAKI;JOKOTA, MASAX+

  摘要：

  DOI：
• 作为产物：
  描述：

  3-(2-fluoro-4-ethoxycarbonylmethyloxy-5-nitrophenyl)-5-isopropylidene-1,3-oxazolidine-2,4-dione 生成 3-[7-fluoro-2H-1,4-benzoxazin-3(4H)-on-6-yl]-5-isopropylidene-1,3-oxazolidine-2,4-dione
  参考文献：
  名称：

  XIRAI, KEHNDZI;FUDZITA, ATSUKO;SATO, XIROSI;XIROSA, XIROAKI;JOKOTA, MASAX+

  摘要：

  DOI：

文献信息

• N-phenylimides, and their production and use
  申请人：Sumitomo Chemical Company, Limited

  公开号：US05322835A1

  公开（公告）日：1994-06-21

  A compound of the formula: ##STR1## wherein X is an oxygen atom or a sulfur atom, Y is a hydrogen atom or a fluorine atom, Z is a methylene group or a group of the formula: N--R.sub.5 (in which R.sub.5 is a hydrogen atom, a C.sub.1 -C.sub.6 alkyl group, a C.sub.3 -C.sub.7 alkenyl group, a C.sub.3 -C.sub.7 alkynyl group, a halo(C.sub.2 -C.sub.6)alkyl group or a C.sub.1 -C.sub.6 alkoxycarbonylmethyl group), R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.6 alkyl group, a C.sub.3 -C.sub.7 alkenyl group, a C.sub.3 -C.sub.7 alkynyl group, a halo(C.sub.2 -C.sub.6)alkyl group, a halo(C.sub.3 -C.sub.7)alkenyl group, a cyano(C.sub.1 -C.sub.6)alkyl group, a C.sub.1 -C.sub.6 alkoxy(C.sub.1 -C.sub.6)alkyl group or a C.sub.1 -C.sub.6 alkoxycarbonylmethyl group, R.sub.2 is a hydrogen atom or a C.sub.1 -C.sub.6 alkyl group; R.sub.3 and R.sub.4 are, the same or different, each is a hydrogen atom or a C.sub.1 -C.sub.6 alkyl group; n is an integer of 0 or 1, which is useful as a herbicide.

  一种化合物的公式为：##STR1## 其中X是氧原子或硫原子，Y是氢原子或氟原子，Z是亚甲基基团或公式：N--R.sub.5（其中R.sub.5是氢原子、C.sub.1 -C.sub.6烷基基团、C.sub.3 -C.sub.7烯基基团、C.sub.3 -C.sub.7炔基基团、卤代（C.sub.2 -C.sub.6）烷基基团或C.sub.1 -C.sub.6烷氧羰基甲基基团），R.sub.1是氢原子、C.sub.1 -C.sub.6烷基基团、C.sub.3 -C.sub.7烯基基团、C.sub.3 -C.sub.7炔基基团、卤代（C.sub.2 -C.sub.6）烷基基团、卤代（C.sub.3 -C.sub.7）烯基基团、氰基（C.sub.1 -C.sub.6）烷基基团、C.sub.1 -C.sub.6烷氧基（C.sub.1 -C.sub.6）烷基基团或C.sub.1 -C.sub.6烷氧羰基甲基基团，R.sub.2是氢原子或C.sub.1 -C.sub.6烷基基团；R.sub.3和R.sub.4是相同或不同，每个是氢原子或C.sub.1 -C.sub.6烷基基团；n是0或1的整数，用作除草剂。
• OXAZOLIDINEDIONE DERIVATIVES AND PRODUCTION THEREOF
  申请人：SAGAMI CHEMICAL RESEARCH CENTER

  公开号：EP0413832A1

  公开（公告）日：1991-02-27

  This invention relates to oxazolidinedione derivatives of general formula (1) and a method of producing the same, wherein R¹ represents a hydrogen atom or a lower alkyl group, and R² represents a hydrogen atom or a lower alkyl group as well. The above compounds serve as an intermediate for the production of benzoxazinone derivatives of general formula(II)selectively in good yields, wherein R¹ represents a hydrogen atom or a lower alkyl group, and R³ represents a hydrogen atom or an alkyl, cyanoalkyl, alkenyl, alkynyl or aralkyl group. Said benzoxazinone derivatives are well-known and useful as a herbicide.

  本发明涉及一般式（1）的噁唑烷二酮衍生物及其制备方法，其中R¹代表氢原子或低碳基团，R²也代表氢原子或低碳基团。上述化合物作为生产苯并噁唑酮衍生物的中间体，选择性地产量良好，其中R¹代表氢原子或低碳基团，R³代表氢原子或烷基、氰基烷基、烯基、炔基或芳基烷基。所述苯并噁唑酮衍生物是众所周知的，并且作为除草剂非常有用。
• N-Phenylimides, and their production and use
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0338533A2

  公开（公告）日：1989-10-25

  A compound of the formula I: wherein X is an oxygen atom or a sulfur atom, Y is a hydrogen atom or a fluorine atom, Z is an oxygen atom, a methylene group or a group of the formula: N-Rs (in which Rs is a hydrogen atom, a C1-C6 alkyl group, a C3-C7 alkenyl group, a C3-C7 alkynyl group, a halo(C2-C6)alkyl group or a C1-C6 alkoxycarbonylmethyl group), R, is a hydrogen atom, a C1-C6 alkyl group, a C3-C7 alkenyl group, a C3-C7 alkynyl group, a halo(C alkyl group, a halo(C3-C7)alkenyl group, a cyano(C1-C6)alkyl group, a C1-C6 alkoxy(C1-C6)alkyl group or a C1-C6 alkoxycarbonylmethyl group, R2 is a hydrogen atom or a C1-C6 alkyl group; R3 and R4 are, the same or different, each a hydrogen atom or a C1-C6 alkyl group; n is an integer of 0 or 1, which is useful as a herbicide.

  式 I 的化合物 其中 X 是氧原子或硫原子，Y 是氢原子或氟原子，Z 是氧原子、亚甲基或式中的基团：N-Rs（其中 Rs 是氢原子、C1-C6 烷基、C3-C7 烯基、C3-C7 炔基、卤代（C2-C6）烷基或 C1-C6 烷氧羰基甲基），R, 是氢原子、C1-C6 烷基、C3-C7 烯基、C3-C7 炔基、卤代（C2-C6）烷基或 C1-C6 烷氧羰基甲基、C3-C7炔基、卤代(C-烷基)、卤代(C3-C7)烯基、氰基(C1-C6)烷基、C1-C6烷氧基(C1-C6)烷基或C1-C6烷氧基羰基甲基，R2是氢原子或C1-C6烷基；R3 和 R4 相同或不同，各自为氢原子或 C1-C6 烷基；n 为 0 或 1 的整数，可用作除草剂。
• Benzoxazinone compounds and herbicidal composition containing the same
  申请人：SAGAMI CHEMICAL RESEARCH CENTER

  公开号：EP0328001A1

  公开（公告）日：1989-08-16

  A benzoxazinone compound represented by the formula (I): wherein R¹ represents a hydrogen atom or an alkyl group, and R² represents a hydrogen atom, an alkyl group, a cyanoalkyl group, an alkenyl group, an alkynyl group or an aralkyl group; a process for preparing the same; and a herbicidal composition comprising the benzoxazinone compound as an active component are disclosed. The above benzoxazinone compounds exhibit a high selectivity for useful crop plants and a strong herbicidal activity with respect to various noxious weeds.

  一种由式(I)代表的苯并恶嗪酮化合物： 其中 R¹ 代表氢原子或烷基，R² 代表氢原子、烷基、氰基烷基、烯基、炔基或芳基；本发明公开了制备该化合物的工艺；以及以该苯并噁嗪酮化合物为活性成分的除草组合物。上述苯并噁嗪酮化合物对有用的作物植物具有很高的选择性，对各种有害杂草具有很强的除草活性。
• XIRAI, KEHNDZI;FUDZITA, ATSUKO;SATO, XIROSI;XIROSEH, XIROAKI;JOKOTA, MASA+
  作者：XIRAI, KEHNDZI、FUDZITA, ATSUKO、SATO, XIROSI、XIROSEH, XIROAKI、JOKOTA, MASA+

  DOI：——

  日期：——