E,E,E-tristyrylphosphine | 154922-43-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: E,E,E-tristyrylphosphine
• 英文别名: tris(E,E,E-styryl)phosphine；tri-styryl-phosphine；Tristyrylphosphine；tris[(E)-2-phenylethenyl]phosphane
• CAS: 154922-43-7
• 化学式: C₂₄H₂₁P
• 分子量: 340.404
• InChiKey: ITCDNAPYHHTRBG-VNQRMFGESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  E,E,E-tristyrylphosphine 在 二甲基亚砜 作用下， 反应 50.0h， 以80%的产率得到E,E,E-tristyrylphosphine oxide
  参考文献：
  名称：

  First Organophosphorus Nonlinear-Optical Media

  摘要：

  DOI：

  10.1023/b:doch.0000017272.85421.34
• 作为产物：
  描述：

  苯乙炔 生成 E,E,E-tristyrylphosphine
  参考文献：
  名称：

  TROFIMOV, B. A.;GUSAROVA, N. K.;MALYSHEVA, S. F.;VYALYX, E. P.;RAXMATULIN+

  摘要：

  DOI：

文献信息

• [EN] NOVEL VINYL PHOSPHINES AND PHOTO-INITIATORS OBTAINABLE THEREFROM<br/>[FR] NOUVELLES PHOSPHINES DE VINYLE ET PHOTO-INITIATEURS POUVANT ÊTRE OBTENUS À PARTIR DE CELLES-CI
  申请人：ETH ZUERICH

  公开号：WO2019175319A1

  公开（公告）日：2019-09-19

  The present invention relates to a highly efficient process to prepare alkyl and vinyl phosphines which are useful as starting materials for novel bisacylphosphine oxides, bisacylphosphinic acids, salts, and derivatives thereof each bearing a vinyl functionality bound to the phosphorous atom as well as a versatile process for the preparation of the latter.

  本发明涉及一种高效的工艺，用于制备烷基和乙烯基膦，这些膦可作为新型双酰膦氧化物、双酰膦酸、盐和衍生物的起始材料，每种衍生物都带有与磷原子结合的乙烯基官能团，以及用于制备后者的多功能工艺。
• Selective formation of ethanol from methanol, hydrogen and carbon monoxide
  申请人：GULF RESEARCH & DEVELOPMENT COMPANY

  公开号：EP0013464A1

  公开（公告）日：1980-07-23

  A process for the sefective formation of ethanol which comprises contacting methanof, hydrogen and carbon monoxide with a catalyst system comprising a source of cobalt, which under the reaction conditions will generate a hydrido cobalt carbonyl complex, such as cobalt acetylacetonate, a tertiary organo Group V A compound of the periodic table, a first promoter comprising an iodine compound an a second promoter comprising a ruthenium compound.

  一种有效生成乙醇的工艺，包括将甲烷、氢气和一氧化碳与催化剂系统接触，催化剂系统由钴源组成，在反应条件下，钴源将生成羰基氢化钴络合物（如乙酰丙酮钴）、元素周期表中的三级有机 V A 族化合物、由碘化合物组成的第一促进剂和由钌化合物组成的第二促进剂。
• Novel catalyst system and process for producing ethanol using said novel catalyst system
  申请人：GULF RESEARCH & DEVELOPMENT COMPANY

  公开号：EP0055887A2

  公开（公告）日：1982-07-14

  A novel catalyst system comprises (1) a cobalt carbonyl, a hydrido cobalt carbonyl or a cobalt-containing material convertible to a cobalt carbonyl or a hydrido cobalt carbonyl, (2) a tertiary organo Group VA compound of the Periodic Table, (3) an iodine compound and (4) a ruthenium compound. A process for selectively producing ethanol comprises introducing into a reaction zone (1) methanol, (2) hydrogen, (3) carbon monoxide and the said novel catalyst and then subjecting the contents of said reaction zone to an elevated temperature and an elevated pressure for a time sufficient to convert methanol to ethanol.

  一种新型催化剂体系包括(1)羰基钴、羰基氢化钴或可转化为羰基钴或羰基氢化钴的含钴材料，(2)元素周期表 VA 族三级有机化合物，(3)碘化合物和(4)钌化合物。一种选择性生产乙醇的工艺，包括将(1)甲醇、(2)氢气、(3)一氧化碳和上述新型催化剂引入反应区，然后将上述反应区的内容物置于高温高压下，时间足以将甲醇转化为乙醇。
• Resin composition for sealing semiconductor and semiconductor device
  申请人：SUMITOMO BAKELITE CO., LTD.

  公开号：US10224259B2

  公开（公告）日：2019-03-05

  The resin composition for sealing semiconductor according to the present invention is characterized by containing a maleimide-based compound represented by the following general formula (1), at least one of the benzoxazine-based compounds represented by the following general formula (2-1) and the following general formula (2-2), a curing catalyst, and an inorganic filler. In the general formulae (1), (2-1) and (2-2), each of X2, X3 and X4 independently represents an alkylene group having 1 to 10 carbon atoms, a group represented by the following general formula (3), a group represented by the formula “—SO2—” or “—CO—”, an oxygen atom or a single bond.

  根据本发明的用于密封半导体的树脂组合物，其特征在于含有由以下通式(1)表示的马来酰亚胺基化合物、由以下通式(2-1)和以下通式(2-2)表示的苯并恶嗪基化合物中的至少一种、固化催化剂和无机填料。 在通式(1)、(2-1)和(2-2)中，X2、X3 和 X4 各自独立地代表具有 1 至 10 个碳原子的亚烷基、下 列通式(3)所代表的基团、式"-SO2-"或"-CO-"所代表的基团、氧原子或单键。
• Gusarova, N. K.; Arbuzova, S. N.; Shaikhudinova, S. I., Russian Journal of General Chemistry, 1993, vol. 63, # 8.1, p. 1224 - 1228
  作者：Gusarova, N. K.、Arbuzova, S. N.、Shaikhudinova, S. I.、Malysheva, S. F.、Rakhmatulina, T. N.、et al.

  DOI：——

  日期：——