2-Ethyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester | 72674-31-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 2-Ethyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester
• 英文别名: Methyl 2-ethylbicyclo[2.2.1]hept-5-ene-2-carboxylate
• CAS: 72674-31-8
• 化学式: C₁₁H₁₆O₂
• 分子量: 180.247
• InChiKey: POQSNRHGKWRZGY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-Ethyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid methyl ester 以80%的产率得到
  参考文献：
  名称：

  PONTICELLO I. S., J. POLYM. SCI.: POLYM. CHEM. ED., 1979, 17, NO 11, 3499-3508

  摘要：

  DOI：
• 作为产物：
  描述：

  5-降冰片烯-2-羧酸甲酯 、 lithium cyclohexylisopropylamide 、 碘乙烷 以70%的产率得到
  参考文献：
  名称：

  PONTICELLO I. S., J. POLYM. SCI.: POLYM. CHEM. ED., 1979, 17, NO 11, 3499-3508

  摘要：

  DOI：

文献信息

• THERMOPLASTIC RESIN COMPOSITION, OPTICAL FILM AND RETARDATION FILM
  申请人：Okaniwa Motoki

  公开号：US20090209705A1

  公开（公告）日：2009-08-20

  Each of the thermoplastic resin composition and the optical film of the present invention comprises a cycloolefin-based polymer (A) and a vinyl-based polymer (B) having a structural unit derived from p-isopropenylphenol. The thermoplastic resin composition and the optical film exhibit excellent compatibility of their components with keeping property of low birefringence inherent in the thermoplastic resin composition comprising the cycloolefln-based polymer and the vinyl-based polymer, and they are excellent in weathering resistance and heat resistance.

  本发明的热塑性树脂组合物和光学膜均包含环氧烷基聚合物（A）和含有源自对异丙基苯酚的结构单元的乙烯基聚合物（B）。热塑性树脂组合物和光学膜展现出其组分的优异相容性，同时保持了环氧烷基聚合物和乙烯基聚合物组成的热塑性树脂组合物固有的低双折射率特性，且它们具有优异的耐候性和耐热性。
• Composition of cyclic olefin addition copolymer and cross-linked material
  申请人：JSR Corporation

  公开号：EP1195397A1

  公开（公告）日：2002-04-10

  A composition comprising a cyclic olefin addition copolymer containing recurring units of the following formulas (1) and (2), and at least one compound selected from (A) a compound acting as an acid when heated to 50°C or higher, (B) a metal compound of an alkoxy compound, aryloxy compound, carboxyl compound, β-diketone compound, halogen compound, or oxide, (C) an organic carboxylic acid, organic phosphoric acid, organic sulfonic acid, ammonia, primary to tertiary amine compound, or quaternary ammonium hydroxide compound. The composition exhibits excellent optical transparency, solvent resistance, dimensional stability, heat resistance, and adhesion to metals and inorganic materials, and suitable for use in optical transparent materials and electronic material parts, to a cross-linked product obtained by crosslinking the composition via siloxane bonds, and to a film, sheet, or coating made from the composition.

  一种包含环状烯烃加成共聚物的组合物，该共聚物含有以下式子(1)和(2)的重复单元、 和至少一种选自以下化合物的化合物：(A) 当加热到 50°C 或更高温度时起酸作用的化合物；(B) 烷氧基化合物、芳氧基化合物、羧基化合物、β-二酮化合物、卤素化合物或氧化物的金属化合物；(C) 有机羧酸、有机磷酸、有机磺酸、氨、伯胺至叔胺化合物或氢氧化季铵盐化合物。该组合物具有优异的光学透明性、耐溶剂性、尺寸稳定性、耐热性以及与金属和无机材料的粘附性，适用于光学透明材料和电子材料部件、通过硅氧烷键交联该组合物而获得的交联产品，以及由该组合物制成的薄膜、薄片或涂层。
• COMPOSITION AND METHOD FOR TEMPORARILY FIXING SOLID
  申请人：JSR Corporation

  公开号：EP1522567A1

  公开（公告）日：2005-04-13

  The present invention relates to a method of temporarily and firmly fixing two solids to each other and to a composition used in the method, which is a method of temporarily fixing, comprising temporarily fixing the two solids to each other with a liquid crystal compound or a composition comprising the liquid crystal compound. This method is used for a method of temporarily fixing a pad for chemical mechanical polishing, for example, to polish a wafer for a semiconductor device fixed on a surface of a base plate, when one solid is a pad for chemical mechanical polishing of a wafer for a semiconductor device and the other is a base plate to fix the pad.

  本发明涉及一种将两个固体暂时牢固地相互固定的方法以及用于该方法的组合物，该方法是一种暂时固定的方法，包括用液晶化合物或包含液晶化合物的组合物将两个固体暂时相互固定。该方法用于临时固定化学机械抛光垫的方法，例如，用于抛光固定在底板表面上的半导体器件晶片，其中一个固体是用于半导体器件晶片化学机械抛光的垫，另一个固体是用于固定垫的底板。
• Resin film and applications thereof
  申请人：JSR CORPORATION

  公开号：US20040106740A1

  公开（公告）日：2004-06-03

  A film for a display device produced by using a transparent (crosslinked) resin film formed of a composition including a cyclic olefin addition copolymer of the present invention has optical transparency, heat resistance, liquid crystal resistance, dimensional stability, and adhesion and is suitably used as an alternative to a glass substrate of a liquid crystal display device and an EL display device. The transparent (crosslinked) resin film can be used as a polarizing film, surface protective film, retardation film, transparent conductive film, light diffusion film, film for an EL display device, transparent conductive composite material, antireflection film, and the like.

  使用由包括本发明环状烯烃加成共聚物在内的组合物形成的透明（交联）树脂薄膜生产的显示设备用薄膜具有光学透明性、耐热性、液晶耐受性、尺寸稳定性和附着力，可适当用作液晶显示设备和电致发光显示设备的玻璃基板的替代品。透明（交联）树脂薄膜可用作偏光膜、表面保护膜、延缓膜、透明导电膜、光扩散膜、EL 显示设备用膜、透明导电复合材料、抗反射膜等。
• Composition and method for temporarily fixing solid
  申请人：——

  公开号：US20040185187A1

  公开（公告）日：2004-09-23

  The present invention relates to a method of temporarily and firmly fixing two solids to each other and to a composition used in the method, which is a method of temporarily fixing, comprising temporarily fixing the two solids to each other with a liquid crystal compound or a composition comprising the liquid crystal compound. This method is used for a method of temporarily fixing a pad for chemical mechanical polishing, for example, to polish a wafer for a semiconductor device fixed on a surface of a base plate, when one solid is a pad for chemical mechanical polishing of a wafer for a semiconductor device and the other is a base plate to fix the pad.

  本发明涉及一种将两个固体暂时牢固地相互固定的方法以及用于该方法的组合物，该方法是一种暂时固定的方法，包括用液晶化合物或包含液晶化合物的组合物将两个固体暂时相互固定。该方法用于临时固定化学机械抛光垫的方法，例如，用于抛光固定在底板表面上的半导体器件晶片，其中一个固体是用于半导体器件晶片化学机械抛光的垫，另一个固体是用于固定垫的底板。