(2-Hydroxy-4-methylphenyl)(2-methylphenyl)methanone | 1023758-42-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-Hydroxy-4-methylphenyl)(2-methylphenyl)methanone
• 英文别名: (2-hydroxy-4-methylphenyl)-(2-methylphenyl)methanone
• CAS: 1023758-42-0
• 化学式: C₁₅H₁₄O₂
• 分子量: 226.275
• InChiKey: ZQBYCFBPNOUFAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2-Hydroxy-4-methylphenyl)(2-methylphenyl)methanone 在 甲酸 、 氯磺酰异氰酸酯 、 sodium hydride 作用下， 以 N,N-二甲基乙酰胺 、 mineral oil 为溶剂， 以18%的产率得到4-(2-methylphenyl)-7-methyl-1,2,3-benzoxathiazine 2,2-dioxide
  参考文献：
  名称：

  Enantioselective Synthesis of Cyclic Sulfamidates via Pd-Catalyzed Hydrogenation

  摘要：

  Using Pd(CF3CO2)(2)/(SS)-f-binaphane as the catalyst, an efficient enantioselective synthesis of cyclic sulfamidates was developed via asymmetric hydrogenation of the corresponding cyclic imines in 2,2,2-trifluoroethanol at room temperature with high enantioselectivities (up to 99% ee).

  DOI：

  10.1021/ol800591u
• 作为产物：
  描述：

  间甲酚 、 邻甲基苯甲酰氯 在 四氯化钛 作用下， 生成 (2-Hydroxy-4-methylphenyl)(2-methylphenyl)methanone
  参考文献：
  名称：

  Enantioselective Synthesis of Cyclic Sulfamidates via Pd-Catalyzed Hydrogenation

  摘要：

  Using Pd(CF3CO2)(2)/(SS)-f-binaphane as the catalyst, an efficient enantioselective synthesis of cyclic sulfamidates was developed via asymmetric hydrogenation of the corresponding cyclic imines in 2,2,2-trifluoroethanol at room temperature with high enantioselectivities (up to 99% ee).

  DOI：

  10.1021/ol800591u

文献信息

• AMPHOLYTIC COPOLYMER, PRODUCTION THEREOF, AND USE OF THE SAME
  申请人：Nguyen Kim Son

  公开号：US20110015280A1

  公开（公告）日：2011-01-20

  The present invention relates to an ampholytic copolymer, to a process for its preparation, to cosmetic or pharmaceutical compositions which comprise at least one such ampholytic copolymer, and to further uses of these copolymers.
• ACTIVE SUBSTANCE COMPOSITION COMPRISING AT LEAST ONE NITROGEN ATOM-CONTAINING, HYPERBRANCHED POLYMER
  申请人：BASF SE

  公开号：US20130123108A1

  公开（公告）日：2013-05-16

  Compositions comprising: (a) at least one hyperbranched polymer comprising nitrogen atoms; and (b) at least one substance exhibiting a solubility in water at 25° C. and 1013 mbar of less than 10 g/l are disclosed along with methods of preparing such compositions.