4,4'-[sulfonylbis(p-phenyleneoxy)]dibenzoic acid | 25423-71-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-[sulfonylbis(p-phenyleneoxy)]dibenzoic acid
• 英文别名: 4-[4-[4-(4-Carboxyphenoxy)phenyl]sulfonylphenoxy]benzoic acid
• CAS: 25423-71-6
• 化学式: C₂₆H₁₈O₈S
• 分子量: 490.49
• InChiKey: WMPZBLHKWPBWCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  35
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  136
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  4,4'-[sulfonylbis(p-phenyleneoxy)]dibenzoic acid 在 氯化亚砜 、 N,N-二甲基甲酰胺 作用下， 反应 4.0h， 生成 4,4'-[sulfonylbis(p-phenyleneoxy)]dibenzoyl chloride
  参考文献：
  名称：

  通过Reissert化学合成杂环单体

  摘要：

  Reissert化合物的化学性质已用于合成活化的二氟四酮单体，该单体包含两个在1,1'-或4,4'-位置连接的异喹啉基偶联部分。这些单体提供了通往新的聚（杂亚芳基醚）族的途径。尝试重排后，含有4,4'-二酮基的新4,4'-偶联双（Reissert化合物）9未能提供所需的二氟四酮单体。然而，类似的含有4,4'-二苄基单元的双（Reissert化合物）19通过醛缩合，中间体酯的水解以及四个苄基部分氧化为酮基的方式完成了该反应。由此制备了新型的二氟四酮单体10。新型双（Reissert化合物）24，28和35由二酰氯和4-（对氟苄基）异喹啉合成。24重排至二酮29，然后氧化4-苄基部分，生成含有1,1'-连接的双异喹啉的二氟四酮单体30。1，1′-连接的双（异喹啉基氟二酮）单体38，与10异构体，是由4-（对氟苄基）Reissert化合物36与对苯二甲醛缩合，酯水解成二醇37制备的。和氧化。在此

  DOI：

  10.1002/pola.24172

文献信息

• Fluorine-Containing Polymerizable Monomer And Polymer Compound Using Same
  申请人：Central Glass Company, Limited

  公开号：US20140148548A1

  公开（公告）日：2014-05-29

  The present invention provides a fluorine-containing fluorenediamine of the formula (2): where R 1 represents one kind of substituent group selected from the group consisting of a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, a C 1 -C 4 alkyl group, a C 1 -C 4 fluoroalkyl group in which any number of hydrogen atoms can be substituted by a fluorine atom, a phenyl group, a methoxy group and a nitro group; R 2 represents one kind of substituent group selected from the group consisting of a hydrogen atom, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, a phenyl group, a naphthyl group, a biphenyl group, a sulfonic acid group, a —C≡C—C(CH 3 ) 2 OH group, a —C≡C—C 6 H 5 group and a —C≡C—Si(CH 3 ) 3 group; HFIP represents a —C(CF 3 ) 2 OH group; and m and n each independently represent an integer of 0 to 2 and satisfy a condition of 1≦m+n≦4.

  本发明提供了一种具有如下公式（2）的含氟芴二胺：其中R1代表从氢原子、氟原子、氯原子、溴原子、C1-C4烷基、C1-C4氟烷基（其中任意数量的氢原子可被氟原子取代）、苯基、甲氧基和硝基等组成的一种取代基；R2代表从氢原子、氟原子、氯原子、溴原子、碘原子、苯基、萘基、联苯基、磺酸基、—C≡C—C(CH3)2OH基、—C≡C—C6H5基和—C≡C—Si(CH3)3基等组成的一种取代基；HFIP代表—C(CF3)2OH基；m和n分别独立地表示0到2的整数，并满足1≦m+n≦4的条件。
• NOVEL COMPOUND, POLYIMIDE RESIN AND METHOD OF PRODUCING THE SAME, PHOTOSENSITIVE RESIN COMPOSITION, PATTERNING METHOD AND METHOD OF FORMING CURED FILM, INTERLAYER INSULATING FILM, SURFACE PROTECTIVE FILM, AND ELECTRONIC COMPONENT
  申请人：International Business Machines Corporation

  公开号：US20210317270A1

  公开（公告）日：2021-10-14

  Provided is a compound that can be used as a base resin for a photosensitive resin composition. The photosensitive resin can form a fine pattern and can achieve high resolution without impairing mechanical strength and solubility. The compound is represented by the general formula (1): wherein Z represents a linear, branched or cyclic divalent hydrocarbon group having 2 to 30 carbon atoms; X 1 to X 3 represent any of —CO 2 —, —CONR X1 —, —O—, —NR X1 —, —S—, —SO 2 —, —SO 3 — and —SO 2 NR X1 — and may be the same as or different from each other, provided that R X1 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 30 carbon atoms; Ar represents a divalent aromatic group having 2 to 30 carbon atoms; L 1 and L 2 independently represent a divalent hydrocarbon group having 1 to 30 carbon atoms; and x and y are each independently 0 or 1.

  提供的是一种可以用作光敏树脂组合物的基树脂的化合物。这种光敏树脂可以形成精细图案，并且可以在不影响机械强度和溶解性的情况下实现高分辨率。该化合物由通式（1）表示：其中Z代表具有2到30个碳原子的线性、支链或环状二价碳氢基团；X1到X3代表任何一种—CO2—、—CONRX1—、—O—、—NRX1—、—S—、—SO2—、—SO3—和—SO2NRX1—中的一种，并且它们可以相同也可以不同，只要RX1是氢原子或具有1到30个碳原子的一价碳氢基团；Ar代表具有2到30个碳原子的二价芳香基团；L1和L2分别代表具有1到30个碳原子的二价碳氢基团；x和y分别独立地为0或1。
• HYGROMORPHIC POLYMERS AND COPOLYMERS HAVING HUMIDITY-DRIVEN MOTILITY
  申请人：Government of the United States, as represented by the Secretary of the Air Force

  公开号：US20170260334A1

  公开（公告）日：2017-09-14

  New diamine monomers bearing sulfone terminated pendant groups, as well as methods for making the same, are provided. The diamine monomers are useful toward making polyamide, polyimide, and poly(amide-imide) polymers and copolymers, which possess hygromorphic properties and demonstrate humidity driven motility.

  提供了带有磺酸终端偏基团的新二胺单体及其制备方法。这些二胺单体可用于制备具有湿敏性能和表现出湿度驱动运动的聚酰胺、聚酰亚胺和聚（酰胺-亚胺）聚合物和共聚物。
• Fluorine-containing polymerizable monomer and polymer compound using same
  申请人：Saegusa Hiroshi

  公开号：US20090023886A1

  公开（公告）日：2009-01-22

  Disclosed is a fluorine-containing polymerizable monomer represented by the formula [1] below. (In the formula [1], a represents an integer of 1-4.) By having a plurality of polymerizable amines in a molecule while containing a hexafluoroisopropyl group, this fluorine-containing polymerizable monomer exhibiting water repellancy, oil repellency, low water absorbency, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index, low dielectric properties, and the like, and thus can be applied to the field of advanced polymer materials.

  公开了一种含氟可聚合单体，其化学式如下所示：[1]（在化学式[1]中，a代表1-4的整数）。该含氟可聚合单体分子中含有多个可聚合胺基，并含有六氟异丙基基团，因此具有耐水性、耐油性、低吸水性、耐热性、耐候性、耐腐蚀性、透明度、光敏性、低折射率、低介电性等特性，可应用于高级聚合物材料领域。
• Fluorine-Containing Polymerizable Monomer and Polymer Compound Using Same
  申请人：Saegusa Hiroshi

  公开号：US20080234460A1

  公开（公告）日：2008-09-25

  Disclosed is a fluorine-containing polymerizable monomer represented by the formula [1] below. (In the formula, A represents a single bond, an oxygen atom, a sulfur atom, CO, CH 2 , SO, SO 2 , C(CH 3 ) 2 , NHCO, C(CF 3 ) 2 , a phenyl or an alicyclic ring; a and b independently represent an integer of 0-2; and 1≦a+b≦4.) Such a fluorine-containing polymerizable monomer can be used as an effective polymerizable monomer exhibiting water repellency, oil repellency, low water absorbency, heat re-sistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index, low dielectric properties and the like. Consequently, the fluorine-containing polymeriz-able monomer can be applied to the field of advanced polymer materials.

  公开了一种含氟可聚合单体，其化学式如下所示[1]。（在公式中，A代表单键，氧原子，硫原子，CO，CH2，SO，SO2，C（CH3）2，NHCO，C（CF3）2，苯基或脂环烷基; a和b分别表示0-2的整数; 1≦a+b≦4。）这种含氟可聚合单体可以用作有效的可聚合单体，表现出耐水性，耐油性，低吸水性，耐热性，耐候性，耐腐蚀性，透明度，光敏性，低折射率，低介电性等特性。因此，这种含氟可聚合单体可以应用于先进聚合材料领域。