N-(1,1-Dimethyl-3-dimethylamino-butyl)-acrylamid | 34730-65-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-(1,1-Dimethyl-3-dimethylamino-butyl)-acrylamid
• 英文别名: N-(1,1-dimethyl-3-dimethylaminobutyl)acrylamide；N-[4-(dimethylamino)-2-methylpentan-2-yl]prop-2-enamide
• CAS: 34730-65-9
• 化学式: C₁₁H₂₂N₂O
• 分子量: 198.308
• InChiKey: PRYNFDAWTYHXCD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  32.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  、 N-(1,1-Dimethyl-3-dimethylaminobutyl)-3-methoxypropionamid 、 sodium hydroxide 、 对苯二酚 、 二氧化碳 反应 4.0h， 以the desired N-(1,1-dimethyl-3-dimethylaminobutyl)acrylamide is obtained at 80°-91° C./0.3-0.4 mm的产率得到N-(1,1-Dimethyl-3-dimethylamino-butyl)-acrylamid
  参考文献：
  名称：

  Polymers of N-aminoalkyl acrylamides

  摘要：

  具有β碳原子上的醚基取代基的N-3-氨基烷基丙酰胺可通过类似的N-3-氧代碳氢代取代酰胺与胺在还原剂（最好是氢气和氢化催化剂）的存在下反应制备而成。所得化合物可在强碱存在下通过热解转化为丙烯酰胺。后者的化合物也可通过β，γ-不饱和胺与丙烯腈在硫酸存在下反应制备而成。它们有助于提高纤维形成聚合物的染色性能，可聚合形成在造纸制造中有用的组合物，并且（在其季铵化形式下）是优秀的絮凝剂。

  公开号：

  US03943114A1

文献信息

• Polymers of N-aminoalkyl acrylamides
  申请人：The Lubrizol Corporation

  公开号：US03943114A1

  公开（公告）日：1976-03-09

  N-3-Aminoalkyl propionamides with an ether substituent on the beta carbon atom are prepared by the reaction of analogous N-3-oxohydrocarbon-substituted amides with an amine in the presence of a reducing agent, preferably hydrogen and a hydrogenation catalyst. The resulting compounds can be converted to acrylamides by pyrolysis in the presence of a strong base. The latter compounds may also be prepared by the reaction of a .beta.,.gamma.-unsaturated amine with an acrylonitrile in the presence of sulfuric acid. They are useful for improving dyeability of fiber-forming polymers and may be polymerized to form compositions which are useful in paper manufacture and (in their quaternized form) are excellent flocculants.

  具有β碳原子上的醚基取代基的N-3-氨基烷基丙酰胺可通过类似的N-3-氧代碳氢代取代酰胺与胺在还原剂（最好是氢气和氢化催化剂）的存在下反应制备而成。所得化合物可在强碱存在下通过热解转化为丙烯酰胺。后者的化合物也可通过β，γ-不饱和胺与丙烯腈在硫酸存在下反应制备而成。它们有助于提高纤维形成聚合物的染色性能，可聚合形成在造纸制造中有用的组合物，并且（在其季铵化形式下）是优秀的絮凝剂。
• Binder for the production of ceramic molded green bodies
  申请人：KURARAY CO., LTD.

  公开号：EP0116300A2

  公开（公告）日：1984-08-22

  A binder for the production of ceramic molded green bodies which comprises a modified polyvinyl alcohol containing either (A) hydrophobic groups having a hydrocarbon group of 4 or more carbon atoms or (A) plus (B) ionic hydrophilic groups in the side chain.

  一种用于生产陶瓷模塑绿体的粘结剂，由改性聚乙烯醇组成，改性聚乙烯醇的侧链中含有(A)具有 4 个或更多碳原子的烃基的疏水基团或(A)加(B)离子亲水基团。
• Crosslinkable cationic emulsion binders and their use as a binder for nonwovens
  申请人：Parsons C. John

  公开号：US20050239356A1

  公开（公告）日：2005-10-27

  The present invention is directed to a cationic polymer emulsion binder that may be combined with a cationic active ingredient and used as a non-woven binder. This combination of cationic binder and cationic active ingredient may occur as a mixture of a cationic binder and at least one cationic active ingredient, which is then applied to loose fibers to form a non-woven; or the combination may occur after a non-woven is formed using a cationic binder, and said non-woven is then contacted with a cationic active ingredient. Non-woven wipes of the invention retain far less cationic active ingredients during use, resulting in less waste and less use of the active ingredients for the same effect as wipes made with anionic or non-ionic binders.

  本发明涉及一种阳离子聚合物乳液粘合剂，可与阳离子活性成分结合，用作无纺布粘合剂。阳离子粘合剂和阳离子活性成分的这种组合可以是阳离子粘合剂和至少一种阳离子活性成分的混合物，然后将其涂在松散的纤维上形成无纺布；也可以是在使用阳离子粘合剂形成无纺布后，再将无纺布与阳离子活性成分接触。与使用阴离子或非离子粘合剂制成的湿巾相比，本发明的无纺布湿巾在使用过程中保留的阳离子活性成分要少得多，从而减少了浪费和活性成分的使用，达到相同的效果。
• CROSSLINKABLE CATIONIC EMULSION BINDERS AND THEIR USE AS A BINDER FOR NONWOVENS
  申请人：Celanese International Corporation

  公开号：EP1448827B1

  公开（公告）日：2007-09-05
• VERWENDUNG VON HYBRIDCOPOLYMEREN ALS SCHUTZKOLLOIDE FÜR POLYMERE
  申请人：Wacker Chemie AG

  公开号：EP2935142B1

  公开（公告）日：2016-10-12