4-tert-butyl-N1-(2-tert-butylphenyl)-N2-(diisopropylphosphino)benzamidine | 1313508-32-5

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 二苄基丁烷木脂素
• 英文名称: 4-tert-butyl-N1-(2-tert-butylphenyl)-N2-(diisopropylphosphino)benzamidine
• 英文别名: 4-tert-butyl-N1-(2-tert-butylphenyl)-N2-(diisopropylphosphino)-benzamidine；4-tert-butyl-N'-(2-tert-butylphenyl)-N-di(propan-2-yl)phosphanylbenzenecarboximidamide
• CAS: 1313508-32-5
• 化学式: C₂₇H₄₁N₂P
• 分子量: 424.61
• InChiKey: LEWOHIULPIVRPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  30
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  、 4-tert-butyl-N1-(2-tert-butylphenyl)benzamidine 、 正丁基锂 、 氯二异丙基膦 在 氯化锂 作用下， 以a yellow semi-solid was isolated (1.9 g, 100%)的产率得到4-tert-butyl-N1-(2-tert-butylphenyl)-N2-(diisopropylphosphino)benzamidine
  参考文献：
  名称：

  Phosphinyl amidine compounds, metal complexes, catalyst systems, and their use to oligomerize or polymerize olefins

  摘要：

  本文描述了N2-膦酰胺化合物、N2-膦酰胺盐、N2-膦酰胺金属盐络合物、N2-膦酰胺盐金属盐络合物。还公开了制备N2-膦酰胺化合物、N2-膦酰胺盐、N2-膦酰胺金属盐络合物和N2-膦酰胺盐金属盐络合物的方法。还公开了利用N2-膦酰胺金属盐络合物和N2-膦酰胺盐金属盐络合物的催化剂系统，以及利用N2-膦酰胺化合物、N2-膦酰胺盐、N2-膦酰胺金属盐络合物和N2-膦酰胺盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。

  公开号：

  US09283555B2

文献信息

• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS
  申请人：Chevron Phillips Chemical Company LP

  公开号：EP2519532B1

  公开（公告）日：2017-03-08
• Phosphinyl Amidine Compounds, Metal Complexes, Catalyst Systems, and Their Use to Oligomerize or Polymerize Olefins
  申请人：Sydora Orson L.

  公开号：US20120309965A1

  公开（公告）日：2012-12-06

  N 2 -phosphinyl amidine compounds, N 2 -phosphinyl amidinates, N 2 -phosphinyl amidine metal salt complexes, N 2 -phosphinyl amidinate metal salt complexes are described. Methods for making N 2 -phosphinyl amidine compounds, N 2 -phosphinyl amidinates, N 2 -phosphinyl amidine metal salt complexes, and N 2 -phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N 2 -phosphinyl amidine metal salt complexes and N 2 -phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N 2 -phosphinyl amidine compounds, N 2 -phosphinyl amidinates, N 2 -phosphinyl amidine metal salt complexes, and N 2 -phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.
• US8680003B2
  申请人：——

  公开号：US8680003B2

  公开（公告）日：2014-03-25
• US9283555B2
  申请人：——

  公开号：US9283555B2

  公开（公告）日：2016-03-15