1-(4-Methoxy-phenyl)-4,8,8,8a-tetramethyl-2-phenyl-8,8a-dihydro-1H-furo[3,4-f]indole-5,7-dione | 145412-12-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯啉
• 英文名称: 1-(4-Methoxy-phenyl)-4,8,8,8a-tetramethyl-2-phenyl-8,8a-dihydro-1H-furo[3,4-f]indole-5,7-dione
• 英文别名: 1-(4-Methoxyphenyl)-4,8,8,8a-tetramethyl-2-phenylfuro[3,4-f]indole-5,7-dione
• CAS: 145412-12-0
• 化学式: C₂₇H₂₅NO₄
• 分子量: 427.5
• InChiKey: GDZCGIBPOICKLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  32
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  55.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1-(4-Methoxy-phenyl)-4,8,8,8a-tetramethyl-2-phenyl-8,8a-dihydro-1H-furo[3,4-f]indole-5,7-dione 生成 3-Isopropylidene-4-[1-[1-(4-methoxy-phenyl)-2-methyl-5-phenyl-1H-pyrrol-3-yl]-eth-(E)-ylidene]-dihydro-furan-2,5-dione
  参考文献：
  名称：

  Studies on Photochromic Mechanism And Applications of Pyrryl Substituted Fulgides

  摘要：

  A series of pyrryl substituted fulgides have been designed and synthesized. Photochromic properties of fulgides have been investigated in various organic solvents. Photochromic mechanism of this kind of fulgides have been studied by means of nanosecond laser flash photolysis technique, both of excited singlet and excited triplet state are involved in the photocyclization process. A sample of optical disk was prepared by spin coating method. Photoinduced electron transfer between pyrryl fulgide and TCNQ has been found and studied by UV-Vis and EPR spectroscopic techniques.

  DOI：

  10.1080/10587259408037787
• 作为产物：
  描述：

  3-Isopropylidene-4-[1-[1-(4-methoxy-phenyl)-2-methyl-5-phenyl-1H-pyrrol-3-yl]-eth-(E)-ylidene]-dihydro-furan-2,5-dione 生成 1-(4-Methoxy-phenyl)-4,8,8,8a-tetramethyl-2-phenyl-8,8a-dihydro-1H-furo[3,4-f]indole-5,7-dione
  参考文献：
  名称：

  Studies on Photochromic Mechanism And Applications of Pyrryl Substituted Fulgides

  摘要：

  A series of pyrryl substituted fulgides have been designed and synthesized. Photochromic properties of fulgides have been investigated in various organic solvents. Photochromic mechanism of this kind of fulgides have been studied by means of nanosecond laser flash photolysis technique, both of excited singlet and excited triplet state are involved in the photocyclization process. A sample of optical disk was prepared by spin coating method. Photoinduced electron transfer between pyrryl fulgide and TCNQ has been found and studied by UV-Vis and EPR spectroscopic techniques.

  DOI：

  10.1080/10587259408037787

文献信息

• AUTHENTICATING A PRODUCT
  申请人：Carr Paul

  公开号：US20100214373A1

  公开（公告）日：2010-08-26

  This invention generally relates to a composition, an apparatus, and a method for authenticating a product. In particular, the invention relates to an ink composition for marking a product with a continuous inkjet printer. The composition includes a visible ink and a UV, visible, and/or IR marker. Marking includes depositing the ink composition on the product with the continuous inkjet printer. A marked product is authenticated with a hand-held apparatus that activates the marker in the mark with UV radiation. Activation of the marker in the mark changes the absorbance/reflectance of visible radiation by the mark without changing the visual appearance of the mark. Authenticity of the product is assessed by a change in absorbance or reflectance of visible radiation by the mark after activation of the mark.
• [EN] AUTHENTICATING A PRODUCT<br/>[FR] AUTHENTIFICATION D'UN PRODUIT
  申请人：AUTHENTIX INC

  公开号：WO2009017506A2

  公开（公告）日：2009-02-05

  This invention generally relates to a composition, an apparatus, and a method for authenticating a product. In particular, the invention relates to an ink composition for marking a product with a continuous inkjet printer. The composition includes a visible ink and a UV, visible, and/or IR marker. Marking includes depositing the ink composition on the product with the continuous inkjet printer. A marked product is authenticated with a hand-held apparatus that activates the marker in the mark with UV radiation. Activation of the marker in the mark changes the absorbance/reflectance of visible radiation by the mark without changing the visual appearance of the mark. Authenticity of the product is assessed by a change in absorbance or reflectance of visible radiation by the mark after activation of the mark.