5-ethyl-3-bromo-2-methyl-nonane | 100386-37-6

• 分子结构分类: 有机化合物 - 有机卤素化合物
• 英文名称: 5-ethyl-3-bromo-2-methyl-nonane
• 英文别名: 5-Aethyl-3-brom-2-methyl-nonan；3-Bromo-5-ethyl-2-methylnonane
• CAS: 100386-37-6
• 化学式: C₁₂H₂₅Br
• 分子量: 249.234
• InChiKey: ZHTIYIPXVJUILS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  5-ethyl-3-bromo-2-methyl-nonane 在 2-甲基丁烷 、 氢化钾 作用下， 生成 5,10-diethyl-7,8-diisopropyl-tetradecane
  参考文献：
  名称：

  Spectra of extremely reduced assemblages: Implications for Mercury

  摘要：

  Abstract— We investigate the possibility that Mercury's crust is very reduced with FeO concentrations of less than ˜0.1 wt%. We believe that such a surface could have a composition of enstatite, plagioclase, diopside, and sulfide, similar to the mineral assemblages found in aubritic meteorites. To test this hypothesis, we investigated the spectra of aubrites and their constituent minerals as analogs for the surface of Mercury. We found that some sulfides have distinctive absorption features in their spectra shortwards of ˜0.6 μm that may be apparent in the spectrum of such an object. Determination of the surface composition of Mercury using orbital x‐ray spectroscopy should easily distinguish between a lunar highlands and enstatite basalt composition since these materials have significant differences in concentrations of Al, Mg, S, and Fe. The strongest argument against Mercury having an enstatite basalt composition is its extreme spectral redness. Significant reddening of the surface of an object (such as Mercury) is believed to require reduction of FeO to nanophase iron, thus requiring a few percent FeO in the material prior to alteration.

  DOI：

  10.1111/j.1945-5100.2002.tb00892.x
• 作为产物：
  描述：

  5-ethyl-2-methylnonan-3-ol 在 氢溴酸 作用下， 生成 5-ethyl-3-bromo-2-methyl-nonane
  参考文献：
  名称：

  Spectra of extremely reduced assemblages: Implications for Mercury

  摘要：

  Abstract— We investigate the possibility that Mercury's crust is very reduced with FeO concentrations of less than ˜0.1 wt%. We believe that such a surface could have a composition of enstatite, plagioclase, diopside, and sulfide, similar to the mineral assemblages found in aubritic meteorites. To test this hypothesis, we investigated the spectra of aubrites and their constituent minerals as analogs for the surface of Mercury. We found that some sulfides have distinctive absorption features in their spectra shortwards of ˜0.6 μm that may be apparent in the spectrum of such an object. Determination of the surface composition of Mercury using orbital x‐ray spectroscopy should easily distinguish between a lunar highlands and enstatite basalt composition since these materials have significant differences in concentrations of Al, Mg, S, and Fe. The strongest argument against Mercury having an enstatite basalt composition is its extreme spectral redness. Significant reddening of the surface of an object (such as Mercury) is believed to require reduction of FeO to nanophase iron, thus requiring a few percent FeO in the material prior to alteration.

  DOI：

  10.1111/j.1945-5100.2002.tb00892.x