1,2-bis(2,4,6-tri-tert-butylphenyl)-3,4-bis(9-fluorenylidene)-1,2-distibacyclobutane | 847144-50-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 1,2-bis(2,4,6-tri-tert-butylphenyl)-3,4-bis(9-fluorenylidene)-1,2-distibacyclobutane
• CAS: 847144-50-7
• 化学式: C₆₄H₇₄Sb₂
• 分子量: 1086.79
• InChiKey: DRCFHVKOBUYKLI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.71
• 重原子数：
  66
• 可旋转键数：
  6
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2,4,6-tri-tert-butylphenyllithium 以 四氢呋喃 、 乙醚 、 正己烷 、 正戊烷 为溶剂， 生成 、 1,2-bis(2,4,6-tri-tert-butylphenyl)-3,4-bis(9-fluorenylidene)-1,2-distibacyclobutane
  参考文献：
  名称：

  The first evidence for a transient stibaallene ArSbCCR2

  摘要：

  Dechlorofluorination of ArSb(F)-C(Cl) = CR2 (CR2 = fluorenylidene, Ar = 2,4,6-tri-tert-butylphenyl) by tert-butyllithium afforded a 3,4-bis(fluorenylidene)-1,2-distibacyclobutane. The formation of the latter probably involves the transient stibaallene ArSb = C = CR2 followed by a head-to-head dimerization via two Sb = C double bonds. Molecular orbital calculations at the ab initio and DFT levels support the head-to-head dimerization of ArSb = C = CR2 with the formation of a 1,2-distibacyclobutane. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.022

文献信息

• The first evidence for a transient stibaallene ArSbCCR2
  作者：Lise Baiget、Henri Ranaivonjatovo、Jean Escudié、Gabriela Cretiu Nemes、Ioan Silaghi-Dumitrescu、Luminita Silaghi-Dumitrescu

  DOI：10.1016/j.jorganchem.2004.09.022

  日期：2005.1

  Dechlorofluorination of ArSb(F)-C(Cl) = CR2 (CR2 = fluorenylidene, Ar = 2,4,6-tri-tert-butylphenyl) by tert-butyllithium afforded a 3,4-bis(fluorenylidene)-1,2-distibacyclobutane. The formation of the latter probably involves the transient stibaallene ArSb = C = CR2 followed by a head-to-head dimerization via two Sb = C double bonds. Molecular orbital calculations at the ab initio and DFT levels support the head-to-head dimerization of ArSb = C = CR2 with the formation of a 1,2-distibacyclobutane. (C) 2004 Elsevier B.V. All rights reserved.