[1-(Pyren-1-ylmethyl)triazol-4-yl]methyl 2-[[7,15,23-tritert-butyl-26,27-bis[2-oxo-2-[[1-(pyren-1-ylmethyl)triazol-4-yl]methoxy]ethoxy]-3,11,19-trioxatetracyclo[19.3.1.15,9.113,17]heptacosa-1(24),5,7,9(27),13(26),14,16,21(25),22-nonaen-25-yl]oxy]acetate | 1263293-77-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: [1-(Pyren-1-ylmethyl)triazol-4-yl]methyl 2-[[7,15,23-tritert-butyl-26,27-bis[2-oxo-2-[[1-(pyren-1-ylmethyl)triazol-4-yl]methoxy]ethoxy]-3,11,19-trioxatetracyclo[19.3.1.15,9.113,17]heptacosa-1(24),5,7,9(27),13(26),14,16,21(25),22-nonaen-25-yl]oxy]acetate
• 英文别名: [1-(pyren-1-ylmethyl)triazol-4-yl]methyl 2-[[7,15,23-tritert-butyl-26,27-bis[2-oxo-2-[[1-(pyren-1-ylmethyl)triazol-4-yl]methoxy]ethoxy]-3,11,19-trioxatetracyclo[19.3.1.15,9.113,17]heptacosa-1(24),5,7,9(27),13(26),14,16,21(25),22-nonaen-25-yl]oxy]acetate
• CAS: 1263293-77-1
• 化学式: C₁₀₂H₉₃N₉O₁₂
• 分子量: 1636.91
• InChiKey: FWLLSKNHXQHBBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.1
• 重原子数：
  123
• 可旋转键数：
  27
• 环数：
  19.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  226
• 氢给体数：
  0
• 氢受体数：
  18

反应信息

• 作为产物：
  描述：

  Prop-2-ynyl 2-[[7,15,23-tritert-butyl-26,27-bis(2-oxo-2-prop-2-ynoxyethoxy)-3,11,19-trioxatetracyclo[19.3.1.15,9.113,17]heptacosa-1(24),5,7,9(27),13(26),14,16,21(25),22-nonaen-25-yl]oxy]acetate 、 1-(叠氮基甲基)芘 在 copper(l) iodide 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 24.0h， 以75.8%的产率得到[1-(Pyren-1-ylmethyl)triazol-4-yl]methyl 2-[[7,15,23-tritert-butyl-26,27-bis[2-oxo-2-[[1-(pyren-1-ylmethyl)triazol-4-yl]methoxy]ethoxy]-3,11,19-trioxatetracyclo[19.3.1.15,9.113,17]heptacosa-1(24),5,7,9(27),13(26),14,16,21(25),22-nonaen-25-yl]oxy]acetate
  参考文献：
  名称：

  yr键联的三唑修饰的高恶acalix [3]芳烃：独特的C 3对称性比例荧光化学传感器，用于Pb 2+

  摘要：

  合成了一种基于均氧磷[3]芳烃的新型荧光化学传感器。与通过by的单体发射增强测试的其他金属离子相比，该荧光传感器对Pb 2+具有高度的选择性。homooxacalix [3] arene的C 3对称结构在开发一种用于重金属离子的新型配比荧光化学传感器方面具有潜在的应用前景。

  DOI：

  10.1021/ol102914t

文献信息

• Ratiometric Fluorescent Receptors for Both Zn²⁺ and H₂PO₄^– Ions Based on a Pyrenyl-Linked Triazole-Modified Homooxacalix[3]arene: A Potential Molecular Traffic Signal with an R-S Latch Logic Circuit
  作者：Xin-long Ni、Xi Zeng、Carl Redshaw、Takehiko Yamato

  DOI：10.1021/jo2007303

  日期：2011.7.15

  A ratiometric fluorescent receptor with a C-3 symmetric structure based on a pyrene-linked triazole-modified homooxacalix[3] arene (L) was synthesized and characterized. This system exhibited an interesting ratiometric detection signal output for targeting cations and anions through switching the excimer emission of pyrene from the "on-off" to the "off-on" type in neutral solution. H-1 NMR titration results suggested that the Zn2+ center of receptor L center dot Zn2+ provided an excellent pathway of organizing anion binding groups for optimal host-guest interactions. It is thus believed that this receptor has potential application in sensing, detection, and recognition of both Zn2+ and H2PO4- ions with different optical signals. In addition, the fluorescence emission changes by the inputs of Zn2+ and H2PO4- ions can be viewed as a combinational R-S latch logic circuit at the molecular level.
• Pyrene-Linked Triazole-Modified Homooxacalix[3]arene: A Unique <i>C</i>₃ Symmetry Ratiometric Fluorescent Chemosensor for Pb²⁺
  作者：Xin-Long Ni、Shi Wang、Xi Zeng、Zhu Tao、Takehiko Yamato

  DOI：10.1021/ol102914t

  日期：2011.2.18

  A new type of fluorescent chemosensor based on homooxacalix[3]arene was synthesized. The fluorescent sensor was highly selective for Pb2+ in comparison with other metal ions tested by enhancement of the monomer emission of pyrene. The C3 symmetric structure of homooxacalix[3]arene has potential application in the development of a new ratiometric fluorescent chemosensor for heavy metal ions.

  合成了一种基于均氧磷[3]芳烃的新型荧光化学传感器。与通过by的单体发射增强测试的其他金属离子相比，该荧光传感器对Pb 2+具有高度的选择性。homooxacalix [3] arene的C 3对称结构在开发一种用于重金属离子的新型配比荧光化学传感器方面具有潜在的应用前景。