tetramethyltellurium(IV) | 123311-08-0

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: tetramethyltellurium(IV)
• 英文别名: Tetramethyl-tellur；tetramethyl tellurium；(trimethyl-λ4-tellanyl)methane
• CAS: 123311-08-0
• 化学式: C₄H₁₂Te
• 分子量: 187.739
• InChiKey: ZSARERCRHNQFCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.95
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  tetramethyltellurium(IV) 在 二氟代氙 作用下， 以 乙腈 为溶剂， 反应 3.0h， 生成 cis-difluoro-tetramethyl-λ⁶-tellane
  参考文献：
  名称：

  Organotellurium(VI) Azides and Halides

  摘要：

  The reaction of azide with organotellurium(VI) halides Ph5TeBr and cis-(biphen)(2)TeF2 (biphen = 2,2'-biphenyldiyl) resulted in the formation and isolation of Ph5TeN3 (1) and cis-(biphen)(2)Te(N-3)(2) (2), which are the first tellurium(VI)-azide species. In addition to spectroscopic data, both crystal structures have been determined. Furthermore, the stability of possible Te(VI) species with higher azide contents PhxTe(N-3)(6-x) and MexTe(N-3)(6-x) as well as the syntheses and properties of their Ph/MexTeFy precursors was investigated, including the crystal structure determination of trans-Ph2TeF4 (3). Ab initio and density functional studies of all molecules regarding the structures and electronic populations were performed.

  DOI：

  10.1021/ja046637q
• 作为产物：
  描述：

  甲基锂 、 四氯化碲 以77%的产率得到
  参考文献：
  名称：

  GEDRIDGE, ROBERT W. (JR);HARRIS, DANIEL C.;HIGA, KELVIN T.;NISSAN, ROBIN +, ORGANOMETALLICS, 8,(1989) N2, C. 2817-2820

  摘要：

  DOI：

文献信息

• Tetra (organyl) tellurium compounds and process for preparing same
  申请人：The United States of America as represented by the Secretary of the Navy

  公开号：US05157154A1

  公开（公告）日：1992-10-20

  Compounds and process for preparation and isolation of tetraorganyl tellurium compounds including: tetraalkyl tellurium and tetraalkenyl tellurium. The products remain relatively stable in the absence of light and air.

  本发明涉及制备和分离四个有机基碲化合物的化合物和过程，包括：四个烷基碲和四个烯基碲。 该产品在无光和空气的情况下相对稳定。
• Process for preparing tetra (organyl) telluride compounds
  申请人：The United States of America as represented by the Secretary of the Navy

  公开号：US05164524A1

  公开（公告）日：1992-11-17

  Compounds and process for preparation and isolation of tetraorganyl tellum compounds including: tetraalkyl tellurium and tetraalkenyl tellurium. The products remain relatively stable in the absence of light and air.

  化合物及其制备和分离方法，包括四个有机基团的碲化合物，包括四个烷基碲和四个烯基碲。在没有光和空气的情况下，这些产品保持相对稳定。
• AHMED, LATIF;MORRISON, JOHN A., J. AMER. CHEM. SOC., 112,(1990) N0, C. 7411-7413
  作者：AHMED, LATIF、MORRISON, JOHN A.

  DOI：——

  日期：——
• Synthesis and characterization of hexamethyltellurium(VI)
  作者：Latif Ahmed、John A. Morrison

  DOI：10.1021/ja00176a061

  日期：1990.9

表征谱图