4-[3-(Acetyloxy)butyl]phenyl acetate | 6973-65-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: 4-[3-(Acetyloxy)butyl]phenyl acetate
• 英文别名: [4-(3-acetyloxybutyl)phenyl] acetate
• CAS: 6973-65-5
• 化学式: C₁₄H₁₈O₄
• 分子量: 250.29
• InChiKey: IDWHTWMEVYBAMH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  联硼酸频那醇酯 、 4-[3-(Acetyloxy)butyl]phenyl acetate 在 六甲基二硅烷 作用下， 以 甲苯 为溶剂， 以60 %的产率得到4-(3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butyl)phenyl acetate
  参考文献：
  名称：

  负载型 Au 催化剂上烷基酯稳定 C(sp3)–O 键的硼化

  摘要：

  我们在此报道，负载型金催化剂有效促进烷基酯的稳定C(sp 3 )–O键的硼基化。使用乙硅烷作为电子源和金纳米粒子作为单电子转移催化剂是通过稳定的C(sp 3 )–O键均裂产生烷基自由基的关键，从而实现双(频那醇)之间的交叉偶联二硼以及直链和环状烷基酯可提供多种烷基硼酸酯。

  DOI：

  10.1021/acs.orglett.4c00225
• 作为产物：
  描述：

  乙酰氯 、 4-(对羟基苯基)-2-丁醇 在 吡啶 作用下， 生成 4-[3-(Acetyloxy)butyl]phenyl acetate
  参考文献：
  名称：

  负载型 Au 催化剂上烷基酯稳定 C(sp3)–O 键的硼化

  摘要：

  我们在此报道，负载型金催化剂有效促进烷基酯的稳定C(sp 3 )–O键的硼基化。使用乙硅烷作为电子源和金纳米粒子作为单电子转移催化剂是通过稳定的C(sp 3 )–O键均裂产生烷基自由基的关键，从而实现双(频那醇)之间的交叉偶联二硼以及直链和环状烷基酯可提供多种烷基硼酸酯。

  DOI：

  10.1021/acs.orglett.4c00225

文献信息

• LEATHER OR LEATHER ARTICLE AND METHOD FOR PRODUCING SAME, HEXAVALENT CHROMIUM TREATMENT AGENT, METHOD FOR TREATING HEXAVALENT CHROMIUM IN CRUDE LEATHER OR CRUDE LEATHER ARTICLE
  申请人：Citizen Watch Co., Ltd.

  公开号：EP3178947A1

  公开（公告）日：2017-06-14

  An object of the invention is to provide a heat-resistant hexavalent chromium removal agent, which is capable of remaining in a leather or leather article for a long period of time and stably detoxifying hexavalent chromium over the long term even when a leather or leather article contains hexavalent chromium, and a leather or leather article, in which the hexavalent chromium content is less than 3 ppm. The leather or leather article of the present invention contains at least: an organic compound (A) having a structure shown in chemical formula (1) and hydroxyphenyl but not aldehyde and carboxyl, which organic compound has a property to reduce hexavalent chromium to trivalent chromium; and trivalent chromium, and the hexavalent chromium content determined in accordance with ISO 17075: 2008-02 is less than 3 ppm.

  本发明的目的是提供一种耐热的六价铬去除剂，即使皮革或皮革制品中含有六价铬，该去除剂也能在皮革或皮革制品中长期存留，并长期稳定地对六价铬进行解毒，同时提供一种六价铬含量低于 3ppm 的皮革或皮革制品。本发明的皮革或皮革制品至少含有：一种有机化合物（A），其结构如化学式（1）所示，具有羟基苯基，但不具有醛和羧基，该有机化合物具有将六价铬还原为三价铬的特性；以及三价铬，且根据 ISO 17075: 2008-02 测定的六价铬含量低于 3 ppm。
• METHOD FOR PRODUCING REPTILE LEATHER OR LEATHER PRODUCT USING HEXAVALENT CHROMIUM TREATMENT AGENT, AND REPTILE LEATHER OR LEATHER PRODUCT USING HEXAVALENT CHROMIUM TREATMENT AGENT
  申请人：Citizen Watch Co., Ltd.

  公开号：EP3409795A1

  公开（公告）日：2018-12-05

  Provided is a method for producing a reptile leather, in which a leather can be treated with a hexavalent chromium treatment agent in the course of leather production without change in the visual appearance of the leather. The method for producing a reptile leather according to the present invention comprises: a chrome tanning step of performing chrome tanning on reptile skin to obtain a leather; a dyeing-fatliquoring step of performing dyeing and fatliquoring simultaneously on the leather subjected to the chrome tanning; and a finishing step of performing finishing on the leather subjected to the dyeing and fatliquoring, the method further comprising a hexavalent chromium treatment step of, prior to the finishing step, applying a hexavalent chromium-reducing compound capable of reducing hexavalent chromium into trivalent chromium to the leather subjected to the chrome tanning in the chrome tanning step.

  本发明提供了一种生产爬行动物皮革的方法，该方法可在皮革生产过程中使用六价铬处理剂对皮革进行处理，而不会改变皮革的视觉外观。根据本发明生产爬行动物皮革的方法包括铬鞣步骤，在爬行动物皮上进行铬鞣以获得皮革； 染色-加脂步骤，在经过铬鞣的皮革上同时进行染色和加脂；该方法还包括一个六价铬处理步骤，即在涂饰步骤之前，在铬鞣步骤中对铬鞣皮革施加能够将六价铬还原成三价铬的六价铬还原化合物。
• Leather or leather article and method for producing same, hexavalent chromium treatment agent, method for treating hexavalent chromium in crude leather or crude leather article
  申请人：CITIZEN WATCH CO., LTD.

  公开号：US10358686B2

  公开（公告）日：2019-07-23

  An object of the invention is to provide a heat-resistant hexavalent chromium removal agent, which is capable of remaining in a leather or leather article for a long period of time and stably detoxifying hexavalent chromium over the long term even when a leather or leather article contains hexavalent chromium, and a leather or leather article, in which the hexavalent chromium content is less than 3 ppm. The leather or leather article of the present invention contains at least: an organic compound (A) having a structure shown in chemical formula (1) and hydroxyphenyl but not aldehyde and carboxyl, which organic compound has a property to reduce hexavalent chromium to trivalent chromium; and trivalent chromium, and the hexavalent chromium content determined in accordance with ISO 17075: 2008-02 is less than 3 ppm.

  本发明的目的是提供一种耐热的六价铬去除剂，即使皮革或皮革制品中含有六价铬，该去除剂也能在皮革或皮革制品中长期存留，并长期稳定地对六价铬进行解毒，同时提供一种六价铬含量低于 3ppm 的皮革或皮革制品。本发明的皮革或皮革制品至少含有：一种有机化合物（A），其结构如化学式（1）所示，具有羟基苯基，但不具有醛和羧基，该有机化合物具有将六价铬还原为三价铬的特性；以及三价铬，且根据 ISO 17075: 2008-02 测定的六价铬含量低于 3 ppm。
• Hexavalent chromium treatment agent and leather or leather article produced using the same
  申请人：CITIZEN WATCH CO., LTD.

  公开号：US10648048B2

  公开（公告）日：2020-05-12

  Provided is a hexavalent chromium treatment agent capable of penetrating inside of a leather and capable of reducing not only hexavalent chromium present in the vicinity of the surface of the leather but also hexavalent chromium present inside the leather into trivalent chromium. The hexavalent chromium treatment agent of the present invention comprises a hexavalent chromium-reducing compound capable of reducing hexavalent chromium into trivalent chromium, a nonionic surfactant, and an aqueous solvent. The hexavalent chromium-reducing compound preferably comprises an organic compound (A) that has a specific structure capable of acting to reduce hexavalent chromium into trivalent chromium, that has a hydroxyphenyl group, and that has no aldehyde groups and no carboxyl groups.

  本发明提供了一种六价铬处理剂，该处理剂能够渗入皮革内部，不仅能够将皮革表面附近的六价铬还原成三价铬，还能将皮革内部的六价铬还原成三价铬。本发明的六价铬处理剂包括一种能够将六价铬还原成三价铬的六价铬还原化合物、一种非离子表面活性剂和一种水性溶剂。六价铬还原化合物最好包括一种有机化合物 (A)，它具有能将六价铬还原成三价铬的特定结构，具有羟基苯基，没有醛基和羧基。
• HEXAVALENT CHROMIUM TREATMENT AGENT, AND LEATHER OR LEATHER PRODUCT USING SAME
  申请人：Citizen Watch Co., Ltd.

  公开号：EP3409741B1

  公开（公告）日：2020-09-02