[1-(3,4-二乙氧苯基)乙基]胺 | 105321-50-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: [1-(3,4-二乙氧苯基)乙基]胺
• 中文别名: 1-(3,4-二乙氧苯基)乙胺；1-(3,4-二乙氧基苯基)-乙胺
• 英文名称: 1-(3,4-Diethoxyphenyl)ethanamine
• CAS: 105321-50-4
• 化学式: C₁₂H₁₉NO₂
• mdl: MFCD03992482
• 分子量: 209.288
• InChiKey: OXUSXEBIIDKQFW-UHFFFAOYSA-N

物化性质

• 沸点：
  305.5±37.0 °C(Predicted)
• 密度：
  1.007±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  15
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  44.5
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 危险等级：
  IRRITANT
• 危险品标志：
  Xi
• 海关编码：
  2922299090

反应信息

• 作为反应物：
  描述：

  [1-(3,4-二乙氧苯基)乙基]胺 、 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 乙腈 为溶剂， 反应 4.0h， 生成 1-[1-(3,4-diethoxy-phenyl)-ethyl]-3-[4-(1-hydroxy-ethyl)-benzyl]-urea
  参考文献：
  名称：

  Bis(2,2,2-trifluoroethyl) Carbonate as a Condensing Agent in One-Pot Parallel Synthesis of Unsymmetrical Aliphatic Ureas

  摘要：

  One-pot parallel synthesis of unsymmetrical aliphatic ureas was achieved with bis(2,2,2-trifluoroethyl) carbonate. The procedure worked well for both the monosubstituted and functionalized alkyl amines and required no special conditions (temperature control, order, or rate of addition). A library of 96 diverse ureas was easily synthesized.

  DOI：

  10.1021/co500025f

文献信息

• Triazine Derivatives, a process for preparing the derivatives, and herbicides containing the derivatives as the effective component
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0191496A2

  公开（公告）日：1986-08-20

  A triazine derivative represented by the general formula: wherein R1 and R2 are each an alkyl group having 1 to 4 carbon atoms, and X1 and X2 are each a halogen atom, an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms, or an alkylthio group having 1 to 4 carbon atoms. This invention also provides a process for efficiently preparing said triazine derivative and a herbicide containing said triazine derivative as effective component.

  由通式代表的三嗪衍生物： 其中 R1 和 R2 分别为具有 1 至 4 个碳原子的烷基，X1 和 X2 分别为卤素原子、具有 1 至 4 个碳原子的烷基、具有 1 至 4 个碳原子的烷氧基或具有 1 至 4 个碳原子的烷硫基。 本发明还提供了一种高效制备所述三嗪衍生物和含有所述三嗪衍生物作为有效成分的除草剂的工艺。
• US4680054A
  申请人：——

  公开号：US4680054A

  公开（公告）日：1987-07-14
• US7439258B2
  申请人：——

  公开号：US7439258B2

  公开（公告）日：2008-10-21
• Bis(2,2,2-trifluoroethyl) Carbonate as a Condensing Agent in One-Pot Parallel Synthesis of Unsymmetrical Aliphatic Ureas
  作者：Andrey V. Bogolubsky、Yurii S. Moroz、Pavel K. Mykhailiuk、Dmitry S. Granat、Sergey E. Pipko、Anzhelika I. Konovets、Roman Doroschuk、Andrey Tolmachev

  DOI：10.1021/co500025f

  日期：2014.6.9

  One-pot parallel synthesis of unsymmetrical aliphatic ureas was achieved with bis(2,2,2-trifluoroethyl) carbonate. The procedure worked well for both the monosubstituted and functionalized alkyl amines and required no special conditions (temperature control, order, or rate of addition). A library of 96 diverse ureas was easily synthesized.