Perfluoro-2-propoxypropionamid | 13140-35-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Perfluoro-2-propoxypropionamid
• 英文别名: 2,3,3,3-Tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propanamide
• CAS: 13140-35-7
• 化学式: C₆H₂F₁₁NO₂
• 分子量: 329.07
• InChiKey: VQHXSBVNMOZRLC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  52.3
• 氢给体数：
  1
• 氢受体数：
  13

反应信息

• 作为反应物：
  描述：

  Perfluoro-2-propoxypropionamid 在 phosphorus pentoxide 作用下， 生成 Perfluor-2-methyl-oxahexan-carbonitril
  参考文献：
  名称：

  Kinetics of the formation of N?-(perfluoroacylimidoyl)perfluoroalkylamidines from perfluoronitriles and perfluoroamidines

  摘要：

  DOI：

  10.1007/bf00921703
• 作为产物：
  描述：

  2,3,3,3-tetrafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)-N'-[(Z)-N-hydroxy-C-[1,2,2,2-tetrafluoro-1-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]ethyl]carbonimidoyl]propanimidamide 、 2,3,3,3-四氟-2-(1,1,2,3,3,3-六氟-2-(1,1,2,3,3,3-六氟-2-(三氟甲氧基)丙氧基)丙氧基)丙酸 生成 Perfluoro-2-propoxypropionamid
  参考文献：
  名称：

  PACIOREK K. J. L.; ITO T. I.; NAKAHARA J. H.; KAUFMAN J.; KRATZER R. H.; +, J. FLUOR. CHEM., 1980, 16, NO 1, 51-62

  摘要：

  DOI：

文献信息

• Methods for Making Functionalized Fluorinated Monomers, Fluorinated Monomers, and Compositions for Making the Same
  申请人：Etna-TEC, Ltd.

  公开号：US20180334417A1

  公开（公告）日：2018-11-22

  A method of making a functionalized fluorinated monomer for use in making oligomers and polymers that can be used to improve surface properties of polymer-derived systems, such as coatings. The method of making a functionalized fluorinated monomer includes reacting at least one fluorinated nucleophilic reactant, such as a fluorinated alcohol, with at least one compound containing at least one epoxide group. Other methods include reaction of a fluorinated alcohol with a cyclic carboxylic anhydride. In another embodiment, a method includes reacting a fluorinated mesylate, tosylate or triflate with an amine, alkoxide or phenoxide. In other embodiments, the method includes reacting a fluorinated alcohol with an alkyl halide, or reacting a fluorinated alkyl halide with an amine. The functionalized fluorinated monomers may be used as intermediates and reacted to modify the functional groups thereon. Further, the functionalized fluorinated monomers may be reacted to form polymers or oligomers, or with polymers or oligomers having functional groups to modify the polymer or oligomer through the functional group thereon,

  一种制备用于制备寡聚物和聚合物的官能化氟化单体的方法，可用于改善聚合物衍生系统（如涂层）的表面性能。制备官能化氟化单体的方法包括将至少一种氟化亲核试剂（如氟化醇）与至少一种含有至少一个环氧基团的化合物反应。其他方法包括将氟化醇与环状羧酸酐反应。在另一实施例中，一种方法包括将氟化甲磺酸酯、对甲苯磺酸酯或三氟甲烷磺酸酯与胺、烷氧基或苯氧基反应。在其他实施例中，该方法包括将氟化醇与烷基卤化物反应，或将氟化烷基卤化物与胺反应。这些官能化氟化单体可用作中间体，并可反应以修改其上的官能基团。此外，这些官能化氟化单体可用于与聚合物或寡聚物反应，或与具有官能基团的聚合物或寡聚物反应，通过其上的官能基团修改聚合物或寡聚物。
• Syntheses and degradations of fluorinated heterocyclics. IV. Imidoylamidoximes, 1,2,4-oxadiazole precursors
  作者：K.J.L. Paciorek、T.I. Ito、J.H. Nakahara、J. Kaufman、R.H. Kratzer、R.W. Rosser

  DOI：10.1016/s0022-1139(00)85148-9

  日期：1980.7
• METHODS FOR MAKING FUNCTIONALIZED FLUORINATED MONOMERS, FLUORINATED MONOMERS, AND COMPOSITIONS FOR MAKING THE SAME
  申请人：Etna-Tec, Ltd

  公开号：EP3635022A1

  公开（公告）日：2020-04-15
• [EN] METHODS FOR MAKING FUNCTIONALIZED FLUORINATED MONOMERS, FLUORINATED MONOMERS, AND COMPOSITIONS FOR MAKING THE SAME<br/>[FR] PROCÉDÉS DE PRÉPARATION DE MONOMÈRES FLUORÉS FONCTIONNALISÉS, MONOMÈRES FLUORÉS ET COMPOSITIONS POUR LES PRÉPARER
  申请人：ETNA TEC LTD

  公开号：WO2018213850A1

  公开（公告）日：2018-11-22

  A method of making a fimctionalized fluonnated monomer for use in making oligomers and polymers that can be used to improve surface properties of polymer-derived systems, such as coatings. The method of making a fimctionalized fluonnated monomer includes reacting at least one fluorinated rmcleophilic reactant, such as a fluonnated alcohol, with at least one compound containing at least one epoxide group. Other methods include reaction of a fluorinated alcohol with a cyclic carboxylic anhydride. In another embodiment, a method includes reacting a fluonnated mesylate, tosyfate or triflate with an amine, alkoxide or phenoxide. In other embodiments, the method includes reacting a fluorinated alcohol with an alkyl hali.de. or reacting a fluorinated alkyl halide with an amine. The fimctionalized fluonnated monomers may be used as intermediates and reacted to modify the functional groups thereon. Further, the functional] zed fluorinated monomers may be reacted to form polymers or oligomers, or with polymers or oligomers having functional groups to modify the polymer or oligomer through the functional group thereon.
• Kinetics of the formation of N?-(perfluoroacylimidoyl)perfluoroalkylamidines from perfluoronitriles and perfluoroamidines
  作者：G. M. Tolmacheva、S. P. Krukovskii、E. L. Berman、V. A. Ponomarenko

  DOI：10.1007/bf00921703

  日期：1976.9