2,4-Oxazolidinedione, 3-(4-chloro-2-fluoro-5-((1-methyl-2-propyn-1-yl)oxy)phenyl)-5-(1-methylethylidene)- | 110956-56-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 2,4-Oxazolidinedione, 3-(4-chloro-2-fluoro-5-((1-methyl-2-propyn-1-yl)oxy)phenyl)-5-(1-methylethylidene)-
• 英文别名: 3-(5-but-3-yn-2-yloxy-4-chloro-2-fluorophenyl)-5-propan-2-ylidene-1,3-oxazolidine-2,4-dione
• CAS: 110956-56-4
• 化学式: C₁₆H₁₃ClFNO₄
• 分子量: 337.73
• InChiKey: LHXJAQGVFIEASH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  55.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  3-(2'-fluoro-4'-chloro-5'-hydroxyphenyl)-5-isopropylidene-1,3-oxazolidine-2,4-dione 、 对甲苯磺酸1-丁炔-3-基酯 生成 2,4-Oxazolidinedione, 3-(4-chloro-2-fluoro-5-((1-methyl-2-propyn-1-yl)oxy)phenyl)-5-(1-methylethylidene)-
  参考文献：
  名称：

  HIRAI, KENJI;FUTIKAMI, TAKAMASA;MURATA, ATSUKO;HIROSE, HIROAKI;YOKOTA, MA+

  摘要：

  DOI：

文献信息

• Methods of preparing fluorobenzene derivatives and related compounds
  申请人：Sagami Chemical Research Center

  公开号：US05391807A1

  公开（公告）日：1995-02-21

  Disclosed are fluorobenzene derivatives, which are important intermediates for producing herbicidal oxazolidinedione derivatives, and methods of producing them. The fluorobenzene derivatives include compounds of a formula (11): ##STR1## where X is a halogen atom, R.sup.3 is a nitro, amino or isocyanato group or R.sup.1 OCONH, and R.sup.1 is an alkyl or phenyl group. Via the intermediates of the invention, oxazolidinedione derivatives can be produced with high yield.

  本发明公开了氟苯衍生物及其制备方法。这些氟苯衍生物是生产除草剂噁唑烷二酮衍生物的重要中间体。所述氟苯衍生物包括公式（11）的化合物：##STR1## 其中X是卤素原子，R.sup.3是硝基、氨基或异氰酸基或R.sup.1 OCONH，而R.sup.1是烷基或苯基。通过本发明的中间体，可以高产地生产噁唑烷二酮衍生物。
• Bis(fluorophenyl) carbonate derivatives
  申请人：Sagami Chemical Research Center

  公开号：US05281742A1

  公开（公告）日：1994-01-25

  Disclosed are fluorobenzene derivatives, which are important intermediates for producing herbicidal oxazolidinedione derivatives, and methods of producing them. The fluorobenzene derivatives include compounds of a formula (11): ##STR1## where X is a halogen atom, R.sup.3 is a nitro, amino or isocyanato group or R.sup.1 OCONH, and R.sup.1 is an alkyl or phenyl group. Via the intermediates of the invention, oxazolidinedione derivatives can be produced with high yield.

  本发明涉及氟苯衍生物，它们是制备除草剂噁唑烷二酮衍生物的重要中间体，以及它们的制备方法。所述氟苯衍生物包括式（11）的化合物：##STR1## 其中X是卤素原子，R.sup.3是硝基，氨基或异氰酸基或R.sup.1 OCONH，R.sup.1是烷基或苯基。通过本发明的中间体，可以高产率地制备噁唑烷二酮衍生物。
• Fluorobenzene derivatives
  申请人：Sagami Chemical Research Center

  公开号：US05344953A1

  公开（公告）日：1994-09-06

  Disclosed are fluorobenzene derivatives, which are important intermediates for producing herbicidal oxazolidinedione derivatives, and methods of producing them. The fluorobenzene derivatives include compounds of a formula (11): ##STR1## where X is a halogen atom, R.sup.3 is a nitro, amino or isocyanato group or R.sup.1 OCONH, and R.sup.1 is an alkyl or phenyl group. Via the intermediates of the invention, oxazolidinedione derivatives can be produced with high yield.

  本发明公开了一种氟苯衍生物，其是制备除草剂噁唑烷二酮衍生物的重要中间体，并公开了制备它们的方法。所述氟苯衍生物包括式（11）的化合物：##STR1## 其中X为卤素原子，R.sup.3为硝基，氨基或异氰酸基或R.sup.1OCONH，R.sup.1为烷基或苯基。通过本发明的中间体，可以高产得到噁唑烷二酮衍生物。
• Herbicidal composition and herbicidal method
  申请人：Kaken Pharmaceutical Co., Ltd.

  公开号：EP0350880A2

  公开（公告）日：1990-01-17

  A herbicidal composition comprising at least one oxazolidinedione derivative expressed by the following formula: (wherein R¹, R² and R³ independently denote hydrogen atoms, halogen atoms, nitro groups, alkyl groups, alkoxy groups, alkenyloxy groups, alkynyloxy groups or cycloalkyloxy groups; R⁴ and R⁵ independently denote hydrogen atoms, alkyl groups or aryl groups or may be combined with each other to form a polymethylene chain; and said alkyl groups, alkoxy groups, alkenyloxy groups, alkynyloxy groups, cycloalkyloxy groups and aryl groups may be substituted); and at least one organic phosphorus herbicide, as acitve ingredients.

  一种除草组合物，包含至少一种由下式表示的噁唑烷二酮衍生物： (其中R¹、R²和R³独立地表示氢原子、卤素原子、硝基、烷基、烷氧基、烯氧基、炔氧基或环烷氧基；R⁴和R⁵独立地表示氢原子、烷基或芳基，或可相互结合形成多亚甲基链；和至少一种有机磷除草剂作为有效成分。
• Adjuvants for novel dry herbicide formulations
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0968649A1

  公开（公告）日：2000-01-05

  This invention pertains to dry formulations of certain fatty alcohol ethoxylated surfactants, which when used at relatively low concentrations, enhance the biological activity of agricultural herbicides.

  本发明涉及某些脂肪醇聚氧乙烯醚表面活性剂的干制剂，当使用浓度相对较低时，可提高农用除草剂的生物活性。