Stabilising materials for halogen-containing polymers and polymer compositions containing the same
申请人:MORTON THIOKOL, INC.
公开号:EP0068640A1
公开(公告)日:1983-01-05
For stabilising halogen-containing polymers compositions are provided which comprise (a) at least one alkyltin mercaptide having the general formula
in which R1 is a C, to C12 straight or branched chain alkyl group, R is a C1 to C20 straight or branched chain alkyl or C2 to C20 alkenyl group, a is 1 or 2 and x is 1 or 2, (b) at least one zinc mercaptoester having the general formula
in which R and x are as above defined, and (c) at least one basic alkali or alkaline earth metal compound, with or without (d) at least one alkyltin sulfide or oxide having the general formula
in which W is oxygen or sulfur and R1 is as defined above. The compound (c) may be an oxide, hydroxide, sulfide, C2 to C, carboxylate, silicate, phosphate, borate or carbonate.
用于稳定含卤聚合物的组合物包括 (a) 至少一种烷基硫醇锡,其通式为
其中 R1 为 C 至 C12 直链或支链烷基,R 为 C1 至 C20 直链或支链烷基或 C2 至 C20 烯基,a 为 1 或 2,x 为 1 或 2,(b) 至少一种具有通式的巯基锌,其中 R 和 x 如上文所定义。
(c) 至少一种碱金属或碱土金属化合物,有或没有 (d) 至少一种硫化烷基锡或氧化烷基锡,其通式为
其中 W 为氧或硫,R1 如上定义。化合物 (c) 可以是氧化物、氢氧化物、硫化物、C2 至 C、羧酸盐、硅酸盐、磷酸盐、硼酸盐或碳酸盐。