1H-苯并咪唑,6-(叠氮甲基)- | 316-18-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 1H-苯并咪唑,6-(叠氮甲基)-
• 中文别名: 屈-3-胺
• 英文名称: 3-aminochrysene
• 英文别名: chrysen-3-amine
• CAS: 316-18-7
• 化学式: C₁₈H₁₃N
• 分子量: 243.308
• InChiKey: YPYPZUAPSWHSPZ-UHFFFAOYSA-N

物化性质

• 沸点：
  506.7±19.0 °C(Predicted)
• 密度：
  1.253±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-acetylaminochrysene 在 盐酸 作用下， 以 乙醇 为溶剂， 反应 10.0h， 以85%的产率得到1H-苯并咪唑,6-(叠氮甲基)-
  参考文献：
  名称：

  Synthesis of Aminochrysenes by the Oxidative Photocyclization of Acetylaminostilbenes.

  摘要：

  在碘和空气存在下，通过乙酰氨基二苯乙烯的氧化光环化反应，然后进行水解，合成了氨基二苯乙烯衍生物。

  DOI：

  10.1248/cpb.41.1853

文献信息

• [EN] ORGANOMETALLIC COMPLEX AND ORGANIC LIGHT-EMITTING ELEMENT USING THE COMPLEX<br/>[FR] COMPLEXE ORGANOMÉTALLIQUE ET ÉLÉMENT ÉLECTROLUMINESCENT ORGANIQUE UTILISANT LEDIT COMPLEXE
  申请人：CANON KK

  公开号：WO2014112657A1

  公开（公告）日：2014-07-24

  Provided is an organic light-emitting element having high light-emitting efficiency and a long element lifetime, the organic light-emitting element including an anode, a cathode, and an organic compound layer placed between the anode and the cathode, in which: the organic compound layer includes an emission layer; the emission layer includes a host and a guest; the host is an aromatic hydrocarbon compound; the guest is an iridium complex of a specific structure; and a content of the host is 50 wt% or more with reference to the total amount of the constituent materials for the emission layer.

  提供的是一种具有高发光效率和长寿命的有机发光元件，该有机发光元件包括阳极、阴极和放置在阳极和阴极之间的有机化合物层，其中：有机化合物层包括发射层；发射层包括主体和客体；主体是芳香烃类化合物；客体是具有特定结构的铱配合物；主体的含量相对于发射层的组分材料总量为50重量％或更多。
• Chromatographic materials for the separation of unsaturated molecules
  申请人：Waters Technologies Corporation

  公开号：US10092894B2

  公开（公告）日：2018-10-09

  The present disclosure relates to a method of separating a compound of interest, particularly unsaturated compound(s) of interest, from a mixture. The compound is separated using a column having a chromatographic stationary phase material for various different modes of chromatography containing a first substituent and a second substituent. The first substituent minimizes compound retention variation over time under chromatographic conditions. The second substituent chromatographically and selectively retains the compound by incorporating one or more aromatic, polyaromatic, heterocyclic aromatic, or polyheterocyclic aromatic hydrocarbon groups, each group being optionally substituted with an aliphatic group.

  本公开涉及一种从混合物中分离相关化合物，特别是相关不饱和化合物的方法。使用色谱柱分离化合物，该色谱柱具有用于各种不同色谱模式的色谱固定相材料，其中含有第一取代基和第二取代基。在色谱条件下，第一取代基可最大程度地减少化合物保留时间的变化。第二取代基通过加入一个或多个芳香族、多芳香族、杂环芳香族或多杂环芳香族烃基团（每个基团可选择被脂肪族基团取代），在色谱上选择性地保留化合物。
• ORGANOMETALLIC COMPLEX AND ORGANIC LIGHT-EMITTING ELEMENT USING THE COMPLEX
  申请人：Canon Kabushiki Kaisha

  公开号：EP2945958B1

  公开（公告）日：2017-09-13
• CHROMATOGRAPHIC MATERIALS FOR THE SEPARATION OF UNSATURATED MOLECULES
  申请人：Waters Technologies Corporation

  公开号：EP3113857A1

  公开（公告）日：2017-01-11
• [EN] CHROMOTOGRAPHIC MATERIALS FOR THE SEPARATION OF UNSATURATED MOLECULES<br/>[FR] MATÉRIAUX CHROMATOGRAPHIQUES POUR LA SÉPARATION DE MOLÉCULES INSATURÉES
  申请人：WATERS TECHNOLOGIES CORP

  公开号：WO2015134317A1

  公开（公告）日：2015-09-11

  The present disclosure relates to a method of separating a compound of interest, particularly unsaturated compound(s) of interest, from a mixture. The compound is separated using a column having a chromatographic stationary phase material for various different modes of chromatography containing a first substituent and a second substituent. The first substituent minimizes compound retention variation over time under chromatographic conditions. The second substituent chromatographically and selectively retains the compound by incorporating one or more aromatic, polyaromatic, heterocyclic aromatic, or polyheterocyclic aromatic hydrocarbon groups, each group being optionally substituted with an aliphatic group.