Bis(1-oxoisononyl) peroxide | 58499-37-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Bis(1-oxoisononyl) peroxide
• 英文别名: 7-methyloctanoyl 7-methyloctaneperoxoate
• CAS: 58499-37-9
• 化学式: C₁₈H₃₄O₄
• 分子量: 314.5
• InChiKey: XKXGWYAQJRXDPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  22
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  過氧化癸醯基 、 过氧化丁二酸 、 2,4-二氯过氧苯甲酰 、 过氧化对氯苯甲酰 生成 Bis(1-oxoisononyl) peroxide
  参考文献：
  名称：

  Energy curable compositions having improved cure speeds

  摘要：

  一种组合物和方法提供了改善聚氨酯前驱体的物理性能和固化速度的方法，无论是否存在自由基聚合单体或寡聚物，都可以使用两种成分催化剂系统。树脂混合物可以通过潜在的有机金属催化剂与有机过氧化物的组合来激活，这种过氧化物可以是过氧化氢或酰过氧化物，以减少固化时间，同时增加系统的断裂能量和正切模量。

  公开号：

  US05212210A1

文献信息

• [EN] PROCESS FOR THE PRODUCTION OF DIACYL PEROXIDES<br/>[FR] PROCÉDÉ DE PRODUCTION DE PEROXYDES DE DIACYLE
  申请人：NOURYON CHEMICALS INT BV

  公开号：WO2020249688A1

  公开（公告）日：2020-12-17

  Process for the production of a diacyl peroxide involving the reaction of an anhydride with hydrogen peroxide, removal of the formed carboxylic acid, production of an anhydride from said carboxylic acid, and recycling of the anhydride within the process.

  生产二酰过氧化物的过程涉及酐与过氧化氢的反应，去除形成的羧酸，从所述羧酸生产酐，并在过程中循环使用酐。
• ASYMMETRIC ORGANIC PEROXIDE, CROSSLINKING AGENT COMPRISING THE SAME, AND METHOD OF CROSSLINKING WITH THE SAME
  申请人：NOF CORPORATION

  公开号：EP1233014A1

  公开（公告）日：2002-08-21

  A crosslinking agent comprising an asymmetry organic peroxide having at least one structure unit of (substituted)benzoylcarbonyloxy group represented by the following formula (1) in the molecule thereof. Environmentally friendly crosslinking agents and crosslinked silicone rubber moldings are provided thereby. Specifically, useful crosslinking agents and crosslinking processes for silicone rubber are provided.

  一种交联剂，包括至少具有分子中表示为以下式（1）的（取代）苯甲酰羰氧基结构单元的不对称有机过氧化物。因此提供了环保的交联剂和交联硅橡胶成型品。具体提供了用于硅橡胶的有用交联剂和交联工艺。
• Hydroxylamine esters as polymerization initiators
  申请人：——

  公开号：US20030216494A1

  公开（公告）日：2003-11-20

  The invention relates to novel cyclic and open-chain hydroxylamine esters and polymerizable compositions comprising these hydroxylamine esters and an ethylenically unsaturated monomer or oligomer. The invention also relates to use as polymerization initiators and to the use of known hydroxylamine esters selected from the group consisting of HALS compounds and the novel hydroxylamine esters for the controlled degradation of polypropylene and for achieving a controlled increase in the molecular weight of polyethylene.

  该发明涉及新型环状和开链羟胺酯以及包括这些羟胺酯和乙烯基不饱和单体或寡聚物的可聚合组合物。该发明还涉及用作聚合引发剂以及用于控制聚丙烯降解和实现聚乙烯分子量控制增加的已知羟胺酯，所述羟胺酯来自HALS化合物和新颖羟胺酯的组合。
• Method for oxidizing hydrocarbons
  申请人：——

  公开号：US20030176733A1

  公开（公告）日：2003-09-18

  The invention relates to a method for oxidizing substrates such as hydrocarbons, waxes or soot. The method involves the use of a compound of formula (I) in which: R1 and R2 represent H, an aliphatic or aromatic alkoxy radical, carboxyl radical, alkoxycarbonyl radical or hydrocarbon radical, each having 1 to 20 hydrocarbon atoms, SO3H, NH2, OH, F, Cl, Br, I and/or NO2, whereby R1 and R2 designate identical or different radicals or R1 and R2 can be linked to one another via a covalent bonding; Q1 and Q2 represent C, CH, N, CR5, each being the same or different; X and Z represent C, S, CH2, each being the same or different; Y represents O and OH; k=0, 1, 2; l=0, 1, 2; m=1 to 3, and; R5 represents one of the meanings of R1. Said compound is used as a catalyst in the presence of a radical initiator, whereby the molar ratio of the catalyst to the hydrocarbon is less than 10 mol %. Peroxy compounds or azo compounds can be used as the radical initiator. Preferred substrates are aliphatic or aromatic hydrocarbons.

  该发明涉及一种氧化底物（如烃、蜡或烟尘）的方法。该方法涉及使用式（I）的化合物，其中：R1和R2代表H、脂肪或芳香烷氧基基、羧基、烷氧羰基基或烃基，每个基有1到20个碳氢原子，SO3H、NH2、OH、F、Cl、Br、I和/或NO2，其中R1和R2表示相同或不同的基团，或者R1和R2可以通过共价键相连；Q1和Q2代表C、CH、N、CR5，每个基相同或不同；X和Z代表C、S、CH2，每个基相同或不同；Y代表O和OH；k=0、1、2；l=0、1、2；m=1到3；R5代表R1的一种含义。所述化合物作为催化剂在自由基引发剂存在下使用，其中催化剂与烃的摩尔比小于10mol％。过氧化物或偶氮化合物可用作自由基引发剂。首选底物为脂肪或芳香烃。
• METHOD FOR PREPARING GLYCIDYLOXYSTYRENE MONOMERS AND POLYMERS THEREOF
  申请人：KUNITSKY KEITH

  公开号：US20080167433A1

  公开（公告）日：2008-07-10

  It was found that glycidyloxystyrenes, including glycidyloxystyrene and substituted glycidyloxystyrene, can be synthesized from hydroxycinnamic acid or substituted hydroxycinnamic acids in a one-pot, two-step process. The substrate can be thermally decarboxylated and then without purification, reacted in the presence of a halomethyl-oxirane and a base. The resulting product can be polymerized or coppolymerized to a fully substituted product.

  发现，包括环氧丙基苯乙烯和取代环氧丙基苯乙烯在内的环氧丙基苯乙烯可以从羟基肉桂酸或取代羟基肉桂酸在一个锅、两步法过程中合成。底物可以在热条件下脱羧，然后在无需纯化的情况下，在卤代甲基环氧烷和碱的存在下反应。得到的产物可以聚合或共聚形成完全取代的产物。