barium(2+);diformate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: barium(2+);diformate
• 化学式: C₂H₂BaO₄
• 分子量: 227.365
• InChiKey: UXFOSWFWQAUFFZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -3.65
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  disodium;carbonate 、 barium(2+);diformate 生成 barium carbonate
  参考文献：
  名称：

  INOUEH, KIESI

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING HYDROGEN
  申请人：Nakahara Masaru

  公开号：US20110158899A1

  公开（公告）日：2011-06-30

  An object of the present invention is to provide a method for producing hydrogen by using formic acid as a feedstock, which provides a solution to problems to be solved for the production of hydrogen on an industrial scale, such as problems of production cost, storability and transportability, and also offers improved convenience. The method for producing hydrogen of the present invention is characterized by heating an ionic liquid containing formic acid. The ionic liquid is preferably an ionic liquid in which a counteranion is a formate anion (i.e., formic acid salt). Such an ionic liquid is, as a medium for the production of hydrogen from formic acid as a feedstock, excellent in terms of reaction selectivity (high-purity hydrogen is produced) and reaction velocity.

  本发明的目的是提供一种使用甲酸作为原料生产氢气的方法，该方法提供了解决工业规模生产氢气所需解决的问题，如生产成本、储存和运输问题，并提供了改进的便利性。本发明的生产氢气的方法的特征在于加热含有甲酸的离子液体。该离子液体最好是一个对阴离子是甲酸根离子（即甲酸盐）的离子液体。这样的离子液体在从甲酸作为原料生产氢气的媒介方面具有很好的反应选择性（产生高纯度的氢气）和反应速度。
• METHOD FOR PRODUCING FORMIC ACID
  申请人：Nakahara Masaru

  公开号：US20120295991A1

  公开（公告）日：2012-11-22

  An object of the present invention is providing a method for producing formic acid under mild reaction conditions and by a simple procedure. As a means for achieving the object, the method for producing formic acid of the present invention is characterized by a reaction between carbon dioxide and hydrogen in the presence of an ionic liquid. According to the present invention, it is possible to generate formic acid effectively, because the method does not require that carbon dioxide be brought into a supercritical state and because no basic substances are required to be added to the reaction system.

  本发明的一个目的是提供一种在温和反应条件下和通过简单的程序生产甲酸的方法。为了实现该目的，本发明的甲酸生产方法特征在于在离子液体存在下，二氧化碳和氢之间的反应。根据本发明，由于该方法不需要将二氧化碳带入超临界状态，也不需要向反应系统中添加任何碱性物质，因此可以有效地产生甲酸。
• Method for producing formic acid
  申请人：Nakahara Masaru

  公开号：US08519013B2

  公开（公告）日：2013-08-27

  An object of the present invention is providing a method for producing formic acid under mild reaction conditions and by a simple procedure. As a means for achieving the object, the method for producing formic acid of the present invention is characterized by a reaction between carbon dioxide and hydrogen in the presence of an ionic liquid. According to the present invention, it is possible to generate formic acid effectively, because the method does not require that carbon dioxide be brought into a supercritical state and because no basic substances are required to be added to the reaction system.

  本发明的目的是提供一种在温和反应条件和简单工艺下生产甲酸的方法。为实现该目的，本发明的甲酸生产方法的特征在于在离子液体的存在下，二氧化碳和氢之间进行反应。根据本发明，由于该方法不需要将二氧化碳带入超临界状态，并且不需要向反应体系中添加任何碱性物质，因此可以有效地产生甲酸。
• Method for producing hydrogen
  申请人：Nakahara Masaru

  公开号：US08449862B2

  公开（公告）日：2013-05-28

  An object of the present invention is to provide a method for producing hydrogen by using formic acid as a feedstock, which provides a solution to problems to be solved for the production of hydrogen on an industrial scale, such as problems of production cost, storability and transportability, and also offers improved convenience. The method for producing hydrogen of the present invention is characterized by heating an ionic liquid containing formic acid. The ionic liquid is preferably an ionic liquid in which a counteranion is a formate anion (i.e., formic acid salt). Such an ionic liquid is, as a medium for the production of hydrogen from formic acid as a feedstock, excellent in terms of reaction selectivity (high-purity hydrogen is produced) and reaction velocity.

  本发明的目的是提供一种利用甲酸作为原料生产氢气的方法，该方法解决了工业规模生产氢气时需要解决的生产成本、储存和运输等问题，并提供了改进的便利性。本发明的生产氢气的方法的特点在于加热含有甲酸的离子液体。所述离子液体最好是一个反离子是甲酸根离子（即甲酸盐）的离子液体。这样的离子液体作为从甲酸原料生产氢气的介质，具有反应选择性（产生高纯度氢气）和反应速率方面的优异性。
• Portnova, S. M.; Krasilov, Yu. I.; Kuznetsov, N. T., Russian Journal of Inorganic Chemistry, <hi>1990</hi>, vol. 35, p. 134 - 136
  作者：Portnova, S. M.、Krasilov, Yu. I.、Kuznetsov, N. T.、Balakaeva, I. V.

  DOI：——

  日期：——