3-(2,4-dichlorophenyl)-2-imino-2,3-dihydrobenzo[d]oxazol-5-yl 4-methylbenzenesulfonate | 1427296-29-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(2,4-dichlorophenyl)-2-imino-2,3-dihydrobenzo[d]oxazol-5-yl 4-methylbenzenesulfonate
• 英文别名: [3-(2,4-Dichlorophenyl)-2-imino-1,3-benzoxazol-5-yl] 4-methylbenzenesulfonate；[3-(2,4-dichlorophenyl)-2-imino-1,3-benzoxazol-5-yl] 4-methylbenzenesulfonate
• CAS: 1427296-29-4
• 化学式: C₂₀H₁₄Cl₂N₂O₄S
• 分子量: 449.314
• InChiKey: IWWGOYRFGKWGHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  88.1
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  (2,4-dichlorophenyl)cyanamide 、 对苯醌 在 potassium carbonate 作用下， 以 乙醇 、 乙腈 为溶剂， 反应 6.0h， 生成 3-(2,4-dichlorophenyl)-2-imino-2,3-dihydrobenzo[d]oxazol-5-yl 4-methylbenzenesulfonate
  参考文献：
  名称：

  Ultrasound-promoted synthesis of novel 2-imino-3-aryl-2,3-dihydrobenzo[d]oxazol-5-ol 2-iminooxazolidines derivatives

  摘要：

  A synthesis of novel 2-iminooxazolidineswas developed by the reaction between arylcyanamides with p-benzoquinone at room temperature under ultrasound irradiation in excellent yields. Also, the chemoselective tosylation of the products were performed at room temperature under ultrasound irradiation in good yields. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.01.069

文献信息

• Ultrasound-promoted synthesis of novel 2-imino-3-aryl-2,3-dihydrobenzo[d]oxazol-5-ol 2-iminooxazolidines derivatives
  作者：Davood Habibi、Mahmoud Nasrollahzadeh、Hesam Sahebekhtiari、Richard Vernon Parish

  DOI：10.1016/j.tet.2013.01.069

  日期：2013.4

  A synthesis of novel 2-iminooxazolidineswas developed by the reaction between arylcyanamides with p-benzoquinone at room temperature under ultrasound irradiation in excellent yields. Also, the chemoselective tosylation of the products were performed at room temperature under ultrasound irradiation in good yields. (C) 2013 Elsevier Ltd. All rights reserved.