| 1011530-91-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1011530-91-8
• 化学式: C₅₄H₁₁₀Al₂Li₂N₂O₄Si₄
• 分子量: 1031.67
• InChiKey: VYNNQRUOOBXOAP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 MeI 作用下， 以 甲苯 为溶剂， 生成 aluminum;bis(trimethylsilyl)methyl-[2,6-di(propan-2-yl)phenyl]azanide;oxolane;diiodide
  参考文献：
  名称：

  Synthesis and Characterization of the Monomeric Vicinal Dianion Li₂(THF)₃[ArNC(SiMe₃)₂] and the Aluminum and Lithium Derivatives of the Amido Ligand [ArNCH(SiMe₃)₂]⁻

  摘要：

  Reaction of the imine ArNC(SiMe3)(2) (1; Ar = 2,6-iPr(2)C(6)H(3)) with LiAlH4 in THF resulted in the formation of the dimeric hydroaluminate [(THF)(2)LiH3AlL](2) (2; L = [ArNCH(SiMe3)(2)](-)). 2 reacted with CH3I to give the monomeric aluminum dihydride LAlH2(THF) (3), which can be converted to the diiodide LAlI2(THF) (4) upon treatment with 2 equiv of Me3SiI. The quasi two-coordinate lithium amide Li(OEt2)L (8) with an intramolecular CH-Li interaction was obtained by the deprotonation of the corresponding amine LH (5) generated from hydrolysis of 2. Reduction of 1 with lithium in THF resulted in the first structurally characterized monomeric C-N vicinal dianion, Li-2(THF)(3)[ArNC(SiMe3)(2)] (6), and the monomeric lithium amide Li(THF)(2)L (7).

  DOI：

  10.1021/om700972a
• 作为产物：
  描述：

  四氢呋喃 、 3-<(2,6-diisopropylphenyl)imino>-2,2,4,4-tetramethyl-2,4-disilapentane 、 lithium aluminium tetrahydride 以 四氢呋喃 为溶剂， 以70%的产率得到
  参考文献：
  名称：

  Synthesis and Characterization of the Monomeric Vicinal Dianion Li₂(THF)₃[ArNC(SiMe₃)₂] and the Aluminum and Lithium Derivatives of the Amido Ligand [ArNCH(SiMe₃)₂]⁻

  摘要：

  Reaction of the imine ArNC(SiMe3)(2) (1; Ar = 2,6-iPr(2)C(6)H(3)) with LiAlH4 in THF resulted in the formation of the dimeric hydroaluminate [(THF)(2)LiH3AlL](2) (2; L = [ArNCH(SiMe3)(2)](-)). 2 reacted with CH3I to give the monomeric aluminum dihydride LAlH2(THF) (3), which can be converted to the diiodide LAlI2(THF) (4) upon treatment with 2 equiv of Me3SiI. The quasi two-coordinate lithium amide Li(OEt2)L (8) with an intramolecular CH-Li interaction was obtained by the deprotonation of the corresponding amine LH (5) generated from hydrolysis of 2. Reduction of 1 with lithium in THF resulted in the first structurally characterized monomeric C-N vicinal dianion, Li-2(THF)(3)[ArNC(SiMe3)(2)] (6), and the monomeric lithium amide Li(THF)(2)L (7).

  DOI：

  10.1021/om700972a