1,10-phenanthroline-bis(pyridine-2-thionato)cadmium(II) | 134587-63-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 1,10-phenanthroline-bis(pyridine-2-thionato)cadmium(II)
• CAS: 134587-63-6
• 化学式: C₂₂H₁₆CdN₄S₂
• 分子量: 512.938
• InChiKey: BLUUMRQZBUPIFO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  锌 、 2-巯基吡啶 、 1,10-菲罗啉 以 乙腈 为溶剂， 生成 1,10-phenanthroline-bis(pyridine-2-thionato)cadmium(II)
  参考文献：
  名称：

  Electrochemical synthesis of pyridine-2-thionato complexes of zinc(II) and cadmium(II): the crystal structure of 1,10-phenanthroline-bis(pyridine-2-thionato)zinc(II)

  摘要：

  Zinc and cadmium pyridine-2-thionato complexes, M(pyt)2, were prepared by direct electrochemical oxidation of the metal into a solution of pyridine-2-thione (pytH) in acetonitrile. Adducts of type [M(pyt)2L] (L = 2,2'-bipyridine or 1,10-phenanthroline) were obtained by addition of the ligand to the electrolyte phase. X-ray structure determination of [Zn(pyt)2phen] shows the molecule to have a distorted octahedral trans-ZnS2N4 core, with average bond distances of 2.182 angstrom for Zn-N(phen), 2.061 angstrom for Zn-N(pyt) and 2.586 angstrom for Zn-S. The vibrational, H-1 and C-13 NMR spectra of the compounds are discussed.

  DOI：

  10.1016/s0277-5387(00)81589-2