1-(2-chloroethoxy)nonyl hydroperoxide | 1255126-71-6

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氢过氧化物
• 英文名称: 1-(2-chloroethoxy)nonyl hydroperoxide
• 英文别名: 1-(2-Chloroethoxy)-1-hydroperoxynonane
• CAS: 1255126-71-6
• 化学式: C₁₁H₂₃ClO₃
• 分子量: 238.755
• InChiKey: RZGNWIKURMOARN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(2-chloroethoxy)nonyl hydroperoxide 在 calcium hypochlorite 作用下， 以 乙腈 为溶剂， 反应 0.17h， 以92%的产率得到Pelargonsaeure-(2-chloraethylester)
  参考文献：
  名称：

  Fragmentation of chloroperoxides: hypochlorite-mediated dehydration of hydroperoxyacetals to esters

  摘要：

  Hypochlorites efficiently dehydrate hydroperoxyacetals to furnish the corresponding esters. The reaction, which can be accomplished with stoichometric Ca(OCl)(2) or with catalytic amounts of t-BuOCl, appears to involve formation and heterolytic fragmentation of secondary chloroperoxides, species not previously described in solution chemistry. (c) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2010.08.068

文献信息

• Fragmentation of chloroperoxides: hypochlorite-mediated dehydration of hydroperoxyacetals to esters
  作者：Thomas J. Fisher、Patrick H. Dussault

  DOI：10.1016/j.tetlet.2010.08.068

  日期：2010.10

  Hypochlorites efficiently dehydrate hydroperoxyacetals to furnish the corresponding esters. The reaction, which can be accomplished with stoichometric Ca(OCl)(2) or with catalytic amounts of t-BuOCl, appears to involve formation and heterolytic fragmentation of secondary chloroperoxides, species not previously described in solution chemistry. (c) 2010 Elsevier Ltd. All rights reserved.