bis{3,4,6-trichloro-2-[(cyclohexylmethoxy)carbonyl]phenyl} oxalate | 1289562-13-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis{3,4,6-trichloro-2-[(cyclohexylmethoxy)carbonyl]phenyl} oxalate
• 英文别名: Bis[3,4,6-trichloro-2-(cyclohexylmethoxycarbonyl)phenyl] oxalate；bis[3,4,6-trichloro-2-(cyclohexylmethoxycarbonyl)phenyl] oxalate
• CAS: 1289562-13-5
• 化学式: C₃₀H₂₈Cl₆O₈
• 分子量: 729.266
• InChiKey: QAGZEOKETQPILM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.7
• 重原子数：
  44
• 可旋转键数：
  13
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  titanium oxide bis(acetylacetonate) 、 3,4,6-三氯-2-羟基苯甲酸 、 环己甲醇 生成 bis{3,4,6-trichloro-2-[(cyclohexylmethoxy)carbonyl]phenyl} oxalate
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• [EN] CHEMICAL LIGHT PRODUCING FORMULATIONS AND DEVICES CONTAINING BRANCHED OXALATE ESTERS<br/>[FR] FORMULATIONS ET DISPOSITIFS CHIMILUMINESCENTS CONTENANT DES ESTERS DE TYPE OXALATES RAMIFIÉS
  申请人：CYALUME TECHNOLOGIES INC

  公开号：WO2011047026A1

  公开（公告）日：2011-04-21

  Chemical light producing systems and the chemiluminescent formulations contained therein are taught which exhibit reduced hydrolysis and thereby are characterized by an inherently long shelf-life and commercial viability. By replacing the typical oxalate ester, e.g. (bis3,4,6-trichloro-2-[(pentoxy)carbonyl] phenyl} oxalate) with a branched chain oxalic acid ester represented by the general formula: wherein the group designated as R contains from 4-15 carbons, wherein the carbon of attachment of R to the oxygen is via a primary carbon, and wherein substructure A is composed of substituents selected from the group including alkyl chains, alkyl rings, aromatic rings and combinations thereof such that R is nonlinear, water hydrolysis of the oxalate ester is retarded. This retardation of the hydrolysis changes the storage constraints of the oxalate ester.

  本文介绍了化学发光系统和其中所含的化学发光配方，其表现出降低的水解反应，因此具有固有的长期保存和商业可行性。通过用一种分支链草酸酯代替典型的草酸酯，例如（双3,4,6-三氯-2-[(戊氧)羰基]苯基}草酸酯），其表示为通式：其中R标示的基团含有4-15个碳，R与氧原子的连接碳原子为一级碳，且亚结构A由选自烷基链，烷基环，芳香环和它们的组合的取代基组成，使得R为非线性结构，草酸酯的水解反应被延缓。这种延缓水解反应改变了草酸酯的储存限制。
• Chemical light producing formulations and devices containing branched oxalate esters
  申请人：Cranor Earl

  公开号：US20110084243A1

  公开（公告）日：2011-04-14

  Chemical light producing systems and the chemiluminescent formulations contained therein are taught which exhibit reduced hydrolysis and thereby are characterized by an inherently long shelf-life and commercial viability. By replacing the typical oxalate ester, e.g. (bis3,4,6-trichloro-2-[(pentoxy)carbonyl]phenyl}oxalate) with a branched chain oxalic acid ester represented by the general formula: wherein the group designated as R contains from 4-15 carbons, wherein the carbon of attachment of R to the oxygen is via a primary carbon, and wherein substructure A is composed of substituents selected from the group including alkyl chains, alkyl rings, aromatic rings and combinations thereof such that R is nonlinear, water hydrolysis of the oxalate ester is retarded. This retardation of the hydrolysis changes the storage constraints of the oxalate ester.

  本发明涉及化学发光系统及其所含的化学发光配方，其表现出降低的水解反应，因此具有固有的长保质期和商业可行性。通过用一种分支链草酸酯代替典型的草酸酯，例如（双3,4,6-三氯-2-[(戊氧)羰基]苯基}草酸酯），所述分支链草酸酯由下列一般式表示：其中被指定为R的基团含有4-15个碳，其中R与氧的连接碳原子为一级碳原子，且亚结构A由选自包括烷基链、烷基环、芳香环和其组合的取代基组成，使得R是非线性的，草酸酯的水解反应被减缓。这种减缓水解反应改变了草酸酯的储存限制。
• Device for dispensing chemiluminescent solution
  申请人：Imperial Toy LLC

  公开号：US10118433B2

  公开（公告）日：2018-11-06

  Devices have a flexible housing with an inside chamber having a closed and open end. A first chemiluminescent fluid is disposed in a breakable container in the chamber, and a second chemiluminescent fluid is in the chamber. A tip assembly is attached to the housing and includes a nib movably disposed in the body, and a filter element may be positioned within the body to prevent passage of broken particles from the container to the nib tip. A resilient element is used to impose an outward biasing force on the nib. A porous material is disposed over an outer surface of the nib tip and securely held in place. The device is activated for use by bending the housing to break the container causing the first and second chemiluminescent fluids to mix and react, providing a chemiluminescent solution that flows to the tip assembly for dispensing onto a desired surface.

  设备有一个柔性外壳，内腔有封闭端和开放端。第一种化学发光流体放置在腔室中的可破损容器中，第二种化学发光流体放置在腔室中。笔尖组件连接到外壳上，包括可移动地设置在主体内的笔尖，过滤元件可设置在主体内，以防止破碎的颗粒从容器进入笔尖。弹性元件用于在笔尖上施加向外的偏压力。多孔材料被放置在笔尖的外表面并牢牢固定。通过弯曲外壳使容器破裂，使第一种和第二种化学发光液体混合并发生反应，从而提供化学发光溶液，该溶液流向笔尖组件，以便分配到所需的表面上。
• COMBINED THERMAL AND CHEMILUMINESCENT REACTION SYSTEM
  申请人：Cyalume Technologies, Inc

  公开号：EP2630215B1

  公开（公告）日：2017-08-02
• BROAD TEMPERATURE PERFORMANCE CHEMILUMINESCENT SYSTEMS AND METHODS
  申请人：Cyalume Technologies, Inc

  公开号：EP3004286B1

  公开（公告）日：2019-08-28