10-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-9,11,12-triphenylbenzo[e]pyrene | 1409939-38-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 10-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-9,11,12-triphenylbenzo[e]pyrene
• CAS: 1409939-38-3
• 化学式: C₆₂H₃₈Br₂
• 分子量: 942.792
• InChiKey: TUTILMLTVGXTRF-UHFFFAOYSA-N

物化性质

• 密度：
  1.375±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  18.93
• 重原子数：
  64.0
• 可旋转键数：
  7.0
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  10-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-9,11,12-triphenylbenzo[e]pyrene 在 sodium periodate 、 rhodium(III) chloride hydrate 作用下， 以 二氯甲烷 、 水 、 乙腈 为溶剂， 反应 26.0h， 以42%的产率得到10-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-9,11,12-triphenylbenzo[e]pyrene-4,5-dione
  参考文献：
  名称：

  Nitrogen-Doped Colloidal Graphene Quantum Dots and Their Size-Dependent Electrocatalytic Activity for the Oxygen Reduction Reaction

  摘要：

  Nitrogen doping has been a powerful way to modify the properties of carbon materials ranging from activated carbon to graphene. Here we report on a solution chemistry approach to nitrogen-doped colloidal graphene quantum dots with well-defined structures. N-doping was demonstrated to significantly affect the properties of the quantum dots, including the emergence of size-dependent electrocatalytic activity for the oxygen reduction reaction.

  DOI：

  10.1021/ja309270h
• 作为产物：
  描述：

  在 四(三苯基膦)钯 、 二苯醚 、 potassium carbonate 作用下， 以 乙醇 、 甲苯 为溶剂， 反应 5.0h， 生成 10-(3'',5''-dibromo-5'-phenyl-[1,1':2',1''-terphenyl]-3-yl)-9,11,12-triphenylbenzo[e]pyrene
  参考文献：
  名称：

  Nitrogen-Doped Colloidal Graphene Quantum Dots and Their Size-Dependent Electrocatalytic Activity for the Oxygen Reduction Reaction

  摘要：

  Nitrogen doping has been a powerful way to modify the properties of carbon materials ranging from activated carbon to graphene. Here we report on a solution chemistry approach to nitrogen-doped colloidal graphene quantum dots with well-defined structures. N-doping was demonstrated to significantly affect the properties of the quantum dots, including the emergence of size-dependent electrocatalytic activity for the oxygen reduction reaction.

  DOI：

  10.1021/ja309270h