7-((diethylamino)coumarin-4-yl)methyl methacrylate | 1163132-59-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 香豆素及其衍生物
• 英文名称: 7-((diethylamino)coumarin-4-yl)methyl methacrylate
• 英文别名: [7-(Diethylamino)-2-oxochromen-4-yl]methyl 2-methylprop-2-enoate
• CAS: 1163132-59-9
• 化学式: C₁₈H₂₁NO₄
• 分子量: 315.369
• InChiKey: KKDQMIGNEDRENY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  55.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  7-(二乙基氨基)-4-(羟基甲基)-2H-苯并吡喃-2-酮 、 甲基丙烯酰氯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 以92%的产率得到7-((diethylamino)coumarin-4-yl)methyl methacrylate
  参考文献：
  名称：

  Babin, Jerome; Pelletier, Maxime; Lepage, Martin, Angewandte Chemie - International EditionAngew. Chem., Int. Ed., 2009, vol. 48, p. 3329 - 3332

  摘要：

  DOI：

文献信息

• OIL REPELLENT COPOLYMER, METHOD FOR ITS PRODUCTION AND OIL REPELLENT TREATMENT SOLUTION
  申请人：Hoshino Taiki

  公开号：US20090281239A1

  公开（公告）日：2009-11-12

  To provide an oil repellent copolymer capable of forming an oil repellent film which is excellent in durability. An oil repellent copolymer characterized by comprising a repeating unit (A) having a polyfluoroalkyl group, a repeating unit (B) having a fluorescent functional group, and a repeating unit (C) having an ester bond other than an ester bond derived from acrylic acid, and/or a hydroxyl group.
• US8338529B2
  申请人：——

  公开号：US8338529B2

  公开（公告）日：2012-12-25
• Babin, Jerome; Pelletier, Maxime; Lepage, Martin, Angewandte Chemie - International EditionAngew. Chem., Int. Ed., 2009, vol. 48, p. 3329 - 3332
  作者：Babin, Jerome、Pelletier, Maxime、Lepage, Martin、Allard, Jean-Francois、Morris, Denis、Zhao, Yue

  DOI：——

  日期：——
• Wavelength-Selective Disruption and Triggered Release with Photolabile Polyelectrolyte Multilayers
  作者：Patricia Gumbley、Damla Koylu、Robert H. Pawle、Bond Umezuruike、Elise Spedden、Cristian Staii、Samuel W. Thomas

  DOI：10.1021/cm403979p

  日期：2014.2.11

  This paper describes photosensitive polyelectrolyte multilayers (PEMs), constructed using layer-by-layer (LbL) self-assembly, which contain polymers that comprise combinations of photocleavable methacrylate esters and photoinert cationic methacrylate esters. The solubility of these polymers in aqueous base depends upon irradiation with either ultraviolet or visible light. PEMs with dialkylaminocoumarin groups dissolve upon irradiation with visible light, while analogous films with nitrobenzyl ester-substituted polymers dissolve upon irradiation with UV light. Wavelength-selective release of fluorescent polymers as guests is demonstrated using this approach.