tert-Butyl-di-p-tolyl-silane | 195608-67-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tert-Butyl-di-p-tolyl-silane
• CAS: 195608-67-4
• 化学式: C₁₈H₂₄Si
• 分子量: 268.474
• InChiKey: KLCNZBQLAQZCSJ-UHFFFAOYSA-N

物化性质

• 沸点：
  339.7±31.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.44
• 重原子数：
  19.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  tert-Butyl-di-p-tolyl-silane 在 过氧化苯甲酰 作用下， 以 四氯化碳 为溶剂， 反应 24.0h， 以88%的产率得到tert-Butyl-chloro-di-p-tolyl-silane
  参考文献：
  名称：

  Photochemical functionalizations of C60 with phenylpolysilanes

  摘要：

  Photolyses of tert-butyl substituted disilanes 1a-1c, and 1i with C-60 result in the formation of 1,16-adduct 2 through silyl radical addition to fullerene. The unusual products, 3, 5, 6 and 7 where the silyl and phenyl groups attached on 1,2-positions of fullerene are also obtained from the reaction of 1d-g and 4. The structures of all these compounds were determined by one- and two-dimensional NMR techniques. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00422-7
• 作为产物：
  描述：

  chloro(di-p-tolyl)silane 、 叔丁基锂 以 正己烷 为溶剂， 以86%的产率得到tert-Butyl-di-p-tolyl-silane
  参考文献：
  名称：

  Photochemical functionalizations of C60 with phenylpolysilanes

  摘要：

  Photolyses of tert-butyl substituted disilanes 1a-1c, and 1i with C-60 result in the formation of 1,16-adduct 2 through silyl radical addition to fullerene. The unusual products, 3, 5, 6 and 7 where the silyl and phenyl groups attached on 1,2-positions of fullerene are also obtained from the reaction of 1d-g and 4. The structures of all these compounds were determined by one- and two-dimensional NMR techniques. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00422-7

文献信息

• Substituents effects on the addition of silyllithium and germyllithium to C60
  作者：Takahiro Kusukawa、Wataru Ando

  DOI：10.1016/s0022-328x(98)00497-5

  日期：1998.6

  Mono-adducts 2 and di-adducts 3 are obtained by the reaction with silyllithium and germyllithium 1 with C-60. The selectivities of the products are controlled by electronic and steric effects of the substituents. Formations of 1,4-adduct 4 and dimer 5 can be obtained in the presence of biphenyl derivatives. (C) 1998 Elsevier Science S.A. All rights reserved.