11-(trichlorosilyl)undecanoic acid isopropyl ester | 820239-07-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 11-(trichlorosilyl)undecanoic acid isopropyl ester
• 英文别名: Propan-2-yl 11-(trichlorosilyl)undecanoate；propan-2-yl 11-trichlorosilylundecanoate
• CAS: 820239-07-4
• 化学式: C₁₄H₂₇Cl₃O₂Si
• 分子量: 361.812
• InChiKey: DIPGADOCOGJKES-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  20
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  十一碳烯酸异丙酯 在 dihydrogen hexachloroplatinate 、 三氯硅烷 作用下， 以 异丙醇 为溶剂， 反应 18.0h， 以94%的产率得到11-(trichlorosilyl)undecanoic acid isopropyl ester
  参考文献：
  名称：

  Carboxylic Acid- and Ester-Functionalized Siloxane Scaffolds on Glass Studied by Broadband Sum Frequency Generation

  摘要：

  Broadband sum frequency generation has been used to characterize glass surfaces functionalized with siloxanes containing terminal carboxylic acid and ester functional groups. omega-Ester silanes can be used in the preparations of ester-functionalized glass surfaces, which yield acid-functionalized surfaces via hydrolysis. This general methodology can be used in environmental, biochemical, or materials science surface chemistry to generate surfaces with tunable physical and chemical properties. Definitive characterization of these carboxylatefunctionalized glass surfaces can be performed in the C-H vibrational frequency region using sum frequency generation.

  DOI：

  10.1021/jp046564x

文献信息

• Carboxylic Acid- and Ester-Functionalized Siloxane Scaffolds on Glass Studied by Broadband Sum Frequency Generation
  作者：Andrea B. Voges、Hind A. Al-Abadleh、Michael J. Musorrafiti、Paul A. Bertin、SonBinh T. Nguyen、Franz M. Geiger

  DOI：10.1021/jp046564x

  日期：2004.12.1

  Broadband sum frequency generation has been used to characterize glass surfaces functionalized with siloxanes containing terminal carboxylic acid and ester functional groups. omega-Ester silanes can be used in the preparations of ester-functionalized glass surfaces, which yield acid-functionalized surfaces via hydrolysis. This general methodology can be used in environmental, biochemical, or materials science surface chemistry to generate surfaces with tunable physical and chemical properties. Definitive characterization of these carboxylatefunctionalized glass surfaces can be performed in the C-H vibrational frequency region using sum frequency generation.